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Article: Multifunctional organic polymeric catalysts and reagents
Title | Multifunctional organic polymeric catalysts and reagents |
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Authors | |
Keywords | Doebner–Knoevenagel reactions Organocatalysis Polymer-supported catalysts Polymer-supported reagents Polystyrene Reductive aldol reactions Wittig reactions |
Issue Date | 2013 |
Publisher | International Union of Pure and Applied Chemistry. The Journal's web site is located at http://www.iupac.org/publications/pac/ |
Citation | Pure and Applied Chemistry, 2013, v. 85 n. 3, p. 543-556 How to Cite? |
Abstract | A series of polystyrenes bearing multiple different functional groups has been synthesized, and these materials have been used as catalysts and reagents in a variety of organic reactions. Polymers functionalized with various combinations of amine, phenol, phosphine, and thiourea groups have been prepared in both non-cross-linked (soluble) and cross-linked (insoluble) formats. Reactions catalyzed by these polymers include Morita–Baylis–Hillman (MBH), alkyne to 1,3-diene isomerization, and decarboxylative Doebner–Knoevenagel reactions. Furthermore, Wittig and tandem Wittig/reduction reactions have been performed using heterogeneous polymeric reagents possessing a combination of amine and phosphine groups. |
Persistent Identifier | http://hdl.handle.net/10722/185712 |
ISSN | 2023 Impact Factor: 2.0 2023 SCImago Journal Rankings: 0.435 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lu, J | en_US |
dc.contributor.author | Toy, PH | en_US |
dc.date.accessioned | 2013-08-20T11:37:37Z | - |
dc.date.available | 2013-08-20T11:37:37Z | - |
dc.date.issued | 2013 | en_US |
dc.identifier.citation | Pure and Applied Chemistry, 2013, v. 85 n. 3, p. 543-556 | en_US |
dc.identifier.issn | 0033-4545 | - |
dc.identifier.uri | http://hdl.handle.net/10722/185712 | - |
dc.description.abstract | A series of polystyrenes bearing multiple different functional groups has been synthesized, and these materials have been used as catalysts and reagents in a variety of organic reactions. Polymers functionalized with various combinations of amine, phenol, phosphine, and thiourea groups have been prepared in both non-cross-linked (soluble) and cross-linked (insoluble) formats. Reactions catalyzed by these polymers include Morita–Baylis–Hillman (MBH), alkyne to 1,3-diene isomerization, and decarboxylative Doebner–Knoevenagel reactions. Furthermore, Wittig and tandem Wittig/reduction reactions have been performed using heterogeneous polymeric reagents possessing a combination of amine and phosphine groups. | - |
dc.language | eng | en_US |
dc.publisher | International Union of Pure and Applied Chemistry. The Journal's web site is located at http://www.iupac.org/publications/pac/ | - |
dc.relation.ispartof | Pure and Applied Chemistry | en_US |
dc.rights | © 2012 IUPAC. The final publication is available at www.degruyter.com | - |
dc.subject | Doebner–Knoevenagel reactions | - |
dc.subject | Organocatalysis | - |
dc.subject | Polymer-supported catalysts | - |
dc.subject | Polymer-supported reagents | - |
dc.subject | Polystyrene | - |
dc.subject | Reductive aldol reactions | - |
dc.subject | Wittig reactions | - |
dc.title | Multifunctional organic polymeric catalysts and reagents | en_US |
dc.type | Article | en_US |
dc.identifier.email | Toy, PH: phtoy@hkucc.hku.hk | en_US |
dc.identifier.authority | Toy, PH=rp00791 | en_US |
dc.description.nature | published_or_final_version | - |
dc.identifier.doi | 10.1351/PAC-CON-12-04-13 | - |
dc.identifier.scopus | eid_2-s2.0-84874431583 | - |
dc.identifier.hkuros | 219572 | en_US |
dc.identifier.volume | 85 | en_US |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 543 | en_US |
dc.identifier.epage | 556 | en_US |
dc.identifier.isi | WOS:000315186600006 | - |
dc.identifier.issnl | 0033-4545 | - |