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Article: Intermolecular (4+3) cycloadditions of aziridinyl enolsilanes

TitleIntermolecular (4+3) cycloadditions of aziridinyl enolsilanes
Authors
Lam, SKLAM, YYSWong, WTChiu, P
Issue Date2014
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2014, v. 50, p. 1738-1741 How to Cite?
DOI: http://dx.doi.org/10.1039/C3CC48266A
AbstractUpon activation by strong Brønsted acids, aziridinyl enolsilanes undergo (4+3) cycloadditions with dienes to afford aminoalkylated cycloheptenones as products. The use of a highly polar medium such as nitroalkane facilitates high cycloaddition yields of up to 99%. Optically pure aziridinyl enolsilanes react to yield (4+3) cycloadducts with up to 99% ee.
Persistent Identifierhttp://hdl.handle.net/10722/200468
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133
ISI Accession Number ID
WOS:000330045400031

 

DC FieldValueLanguage
dc.contributor.authorLam, SKen_US
dc.contributor.authorLAM, YYSen_US
dc.contributor.authorWong, WTen_US
dc.contributor.authorChiu, Pen_US
dc.date.accessioned2014-08-21T06:48:32Z-
dc.date.available2014-08-21T06:48:32Z-
dc.date.issued2014en_US
dc.identifier.citationChemical Communications, 2014, v. 50, p. 1738-1741en_US
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/200468-
dc.description.abstractUpon activation by strong Brønsted acids, aziridinyl enolsilanes undergo (4+3) cycloadditions with dienes to afford aminoalkylated cycloheptenones as products. The use of a highly polar medium such as nitroalkane facilitates high cycloaddition yields of up to 99%. Optically pure aziridinyl enolsilanes react to yield (4+3) cycloadducts with up to 99% ee.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofChemical Communicationsen_US
dc.titleIntermolecular (4+3) cycloadditions of aziridinyl enolsilanesen_US
dc.typeArticleen_US
dc.identifier.emailLam, SK: h9808243@hkusua.hku.hken_US
dc.identifier.emailWong, WT: wtwong@hku.hken_US
dc.identifier.emailChiu, P: pchiu@hku.hken_US
dc.identifier.authorityLam, SK=rp00720en_US
dc.identifier.authorityWong, WT=rp00811en_US
dc.identifier.authorityChiu, P=rp00680en_US
dc.identifier.doi10.1039/C3CC48266Aen_US
dc.identifier.pmid24394550-
dc.identifier.scopuseid_2-s2.0-84892880340-
dc.identifier.hkuros232031en_US
dc.identifier.volume50en_US
dc.identifier.spage1738en_US
dc.identifier.epage1741en_US
dc.identifier.eissn1364-548X-
dc.identifier.isiWOS:000330045400031-
dc.publisher.placeLondonen_US
dc.identifier.issnl1359-7345-

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