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Article: A high-capacity dual-electrolyte aluminum/air electrochemical cell

TitleA high-capacity dual-electrolyte aluminum/air electrochemical cell
Authors
Issue Date2014
PublisherRSC Publications. The Journal's web site is located at http://pubs.rsc.org/en/journals/journalissues/ra
Citation
RSC Advances, 2014, v. 4 n. 58, p. 30857-30863 How to Cite?
AbstractA novel dual-electrolyte aluminum/air cell (DEAAC), consisting of an aluminum metal anode in an organic anolyte, an anion polymer exchange membrane, and an air electrode in an aqueous alkaline catholyte, has been investigated. The anion membrane separates the organic anolyte from the aqueous catholyte, while allowing hydroxide ions to pass through. The DEAAC exhibited an open circuit voltage (VOC) of 1.6 V and a short current density (JSC) of 65 mA cm−2. With kitchen aluminum foil as the fuel, the DEAAC achieved an anodic capacity of 6000 mA h cm−3 at a discharge current density of 30 mA cm−2, which is much higher than the lithium's theoretical capacity of 2060 mA h cm−3. The anodic capacity of the DEAAC increased by 30–50 folds at different discharge current densities compared with that of a traditional alkaline Al/air cell (AAC). Overall, the DEAAC is promising as an electrochemical energy storage device because it has no detrimental hydrogen generation problem and exhibits very high anodic capacity.
Persistent Identifierhttp://hdl.handle.net/10722/200664
ISSN
2023 Impact Factor: 3.9
2023 SCImago Journal Rankings: 0.715
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWang, L-
dc.contributor.authorLiu, F-
dc.contributor.authorWang, W-
dc.contributor.authorYang, G-
dc.contributor.authorZheng, D-
dc.contributor.authorWu, Z-
dc.contributor.authorLeung, MKH-
dc.date.accessioned2014-08-21T06:54:17Z-
dc.date.available2014-08-21T06:54:17Z-
dc.date.issued2014-
dc.identifier.citationRSC Advances, 2014, v. 4 n. 58, p. 30857-30863-
dc.identifier.issn2046-2069-
dc.identifier.urihttp://hdl.handle.net/10722/200664-
dc.description.abstractA novel dual-electrolyte aluminum/air cell (DEAAC), consisting of an aluminum metal anode in an organic anolyte, an anion polymer exchange membrane, and an air electrode in an aqueous alkaline catholyte, has been investigated. The anion membrane separates the organic anolyte from the aqueous catholyte, while allowing hydroxide ions to pass through. The DEAAC exhibited an open circuit voltage (VOC) of 1.6 V and a short current density (JSC) of 65 mA cm−2. With kitchen aluminum foil as the fuel, the DEAAC achieved an anodic capacity of 6000 mA h cm−3 at a discharge current density of 30 mA cm−2, which is much higher than the lithium's theoretical capacity of 2060 mA h cm−3. The anodic capacity of the DEAAC increased by 30–50 folds at different discharge current densities compared with that of a traditional alkaline Al/air cell (AAC). Overall, the DEAAC is promising as an electrochemical energy storage device because it has no detrimental hydrogen generation problem and exhibits very high anodic capacity.-
dc.languageeng-
dc.publisherRSC Publications. The Journal's web site is located at http://pubs.rsc.org/en/journals/journalissues/ra-
dc.relation.ispartofRSC Advances-
dc.titleA high-capacity dual-electrolyte aluminum/air electrochemical cell-
dc.typeArticle-
dc.identifier.emailLiu, F: fordliu@hku.hk-
dc.identifier.authorityLiu, F=rp01358-
dc.description.naturelink_to_OA_fulltext-
dc.identifier.doi10.1039/C4RA05222F-
dc.identifier.scopuseid_2-s2.0-84904810141-
dc.identifier.hkuros234291-
dc.identifier.volume4-
dc.identifier.issue58-
dc.identifier.spage30857-
dc.identifier.epage30863-
dc.identifier.isiWOS:000340500300057-
dc.publisher.placeUnited Kingdom-
dc.identifier.issnl2046-2069-

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