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Article: Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
| Title | Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4] |
|---|---|
| Authors | |
| Keywords | Sulfido complexes Crystal structure Alkylation reactions Platinum complexes Thiolate complexes |
| Issue Date | 2010 |
| Citation | Inorganica Chimica Acta, 2010, v. 363, n. 13, p. 3558-3568 How to Cite? |
| Abstract | Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved. |
| Persistent Identifier | http://hdl.handle.net/10722/219373 |
| ISSN | 2021 Impact Factor: 3.118 2020 SCImago Journal Rankings: 0.437 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ujam, Oguejiofo T. | - |
| dc.contributor.author | Devoy, Sarah M. | - |
| dc.contributor.author | Henderson, William | - |
| dc.contributor.author | Nicholson, Brian K. | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:56:55Z | - |
| dc.date.available | 2015-09-23T02:56:55Z | - |
| dc.date.issued | 2010 | - |
| dc.identifier.citation | Inorganica Chimica Acta, 2010, v. 363, n. 13, p. 3558-3568 | - |
| dc.identifier.issn | 0020-1693 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219373 | - |
| dc.description.abstract | Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganica Chimica Acta | - |
| dc.subject | Sulfido complexes | - |
| dc.subject | Crystal structure | - |
| dc.subject | Alkylation reactions | - |
| dc.subject | Platinum complexes | - |
| dc.subject | Thiolate complexes | - |
| dc.title | Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4] | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/j.ica.2010.07.011 | - |
| dc.identifier.scopus | eid_2-s2.0-77957706600 | - |
| dc.identifier.volume | 363 | - |
| dc.identifier.issue | 13 | - |
| dc.identifier.spage | 3558 | - |
| dc.identifier.epage | 3568 | - |
| dc.identifier.isi | WOS:000282677800056 | - |
| dc.identifier.issnl | 0020-1693 | - |