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Article: Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes

TitleComplete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes
Authors
Wei, BingLi, SihaiLee, Hian KeeHor, T. S Andy
KeywordsDebromination
Polybromobenzenes
Palladium
Metallocenyl phosphine
Diphosphine
Issue Date1997
Citation
Journal of Molecular Catalysis A: Chemical, 1997, v. 126, n. 2-3, p. L83-L88 How to Cite?
DOI: http://dx.doi.org/10.1016/S1381-1169(97)00144-1
AbstractPd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base.
Persistent Identifierhttp://hdl.handle.net/10722/219423
ISSN
1381-1169
2018 Impact Factor: 5.008
ISI Accession Number ID
WOS:000071005800001

 

DC FieldValueLanguage
dc.contributor.authorWei, Bing-
dc.contributor.authorLi, Sihai-
dc.contributor.authorLee, Hian Kee-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:02Z-
dc.date.available2015-09-23T02:57:02Z-
dc.date.issued1997-
dc.identifier.citationJournal of Molecular Catalysis A: Chemical, 1997, v. 126, n. 2-3, p. L83-L88-
dc.identifier.issn1381-1169-
dc.identifier.urihttp://hdl.handle.net/10722/219423-
dc.description.abstractPd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base.-
dc.languageeng-
dc.relation.ispartofJournal of Molecular Catalysis A: Chemical-
dc.subjectDebromination-
dc.subjectPolybromobenzenes-
dc.subjectPalladium-
dc.subjectMetallocenyl phosphine-
dc.subjectDiphosphine-
dc.titleComplete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S1381-1169(97)00144-1-
dc.identifier.scopuseid_2-s2.0-0031458081-
dc.identifier.volume126-
dc.identifier.issue2-3-
dc.identifier.spageL83-
dc.identifier.epageL88-
dc.identifier.isiWOS:000071005800001-
dc.identifier.issnl1381-1169-

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