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- Publisher Website: 10.1016/S1381-1169(97)00144-1
- Scopus: eid_2-s2.0-0031458081
- WOS: WOS:000071005800001
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Article: Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes
Title | Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes |
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Authors | |
Keywords | Debromination Polybromobenzenes Palladium Metallocenyl phosphine Diphosphine |
Issue Date | 1997 |
Citation | Journal of Molecular Catalysis A: Chemical, 1997, v. 126, n. 2-3, p. L83-L88 How to Cite? |
Abstract | Pd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base. |
Persistent Identifier | http://hdl.handle.net/10722/219423 |
ISSN | 2018 Impact Factor: 5.008 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wei, Bing | - |
dc.contributor.author | Li, Sihai | - |
dc.contributor.author | Lee, Hian Kee | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:02Z | - |
dc.date.available | 2015-09-23T02:57:02Z | - |
dc.date.issued | 1997 | - |
dc.identifier.citation | Journal of Molecular Catalysis A: Chemical, 1997, v. 126, n. 2-3, p. L83-L88 | - |
dc.identifier.issn | 1381-1169 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219423 | - |
dc.description.abstract | Pd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Molecular Catalysis A: Chemical | - |
dc.subject | Debromination | - |
dc.subject | Polybromobenzenes | - |
dc.subject | Palladium | - |
dc.subject | Metallocenyl phosphine | - |
dc.subject | Diphosphine | - |
dc.title | Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S1381-1169(97)00144-1 | - |
dc.identifier.scopus | eid_2-s2.0-0031458081 | - |
dc.identifier.volume | 126 | - |
dc.identifier.issue | 2-3 | - |
dc.identifier.spage | L83 | - |
dc.identifier.epage | L88 | - |
dc.identifier.isi | WOS:000071005800001 | - |
dc.identifier.issnl | 1381-1169 | - |