File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ic011181o
- Scopus: eid_2-s2.0-0037121895
- PMID: 12470082
- WOS: WOS:000179797700038
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au)
| Title | Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au) |
|---|---|
| Authors | |
| Issue Date | 2002 |
| Citation | Inorganic Chemistry, 2002, v. 41, n. 25, p. 6838-6845 How to Cite? |
| Abstract | Novel electroactive multimetallic compounds based on the {Pt2(μ2-S)2M} core, viz. [Pt2(PPh3)4 (μ3-S)2HgFc]PF6 (1) [Fc = (η5-C5H4)Fe(η5- C5H5)] and [Pt2(PPh3)4 (μ3-S)2Hg2Fc′] (PF6)2 (2) [Fc′ = Fe(η5-C5H4)2], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt2(PPh3)4 (μ3-S)2HgPPh3] (PF6)2 (3), [Pt2(PPh3)4(μ2-S) (μ3-S)HgPh]PF6 (4), and [Pt2(PPh3)4-(μ2-S) (μ3-S)AuPPh3]PF6 (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation. |
| Persistent Identifier | http://hdl.handle.net/10722/219461 |
| ISSN | 2021 Impact Factor: 5.436 2020 SCImago Journal Rankings: 1.348 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Xu, Xingling | - |
| dc.contributor.author | Audi Fong, S. W. | - |
| dc.contributor.author | Li, Zhaohui | - |
| dc.contributor.author | Loh, Zhi Heng | - |
| dc.contributor.author | Zhao, Feng | - |
| dc.contributor.author | Vittal, Jagadese J. | - |
| dc.contributor.author | Henderson, William | - |
| dc.contributor.author | Khoo, Soo Beng | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:08Z | - |
| dc.date.available | 2015-09-23T02:57:08Z | - |
| dc.date.issued | 2002 | - |
| dc.identifier.citation | Inorganic Chemistry, 2002, v. 41, n. 25, p. 6838-6845 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219461 | - |
| dc.description.abstract | Novel electroactive multimetallic compounds based on the {Pt2(μ2-S)2M} core, viz. [Pt2(PPh3)4 (μ3-S)2HgFc]PF6 (1) [Fc = (η5-C5H4)Fe(η5- C5H5)] and [Pt2(PPh3)4 (μ3-S)2Hg2Fc′] (PF6)2 (2) [Fc′ = Fe(η5-C5H4)2], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt2(PPh3)4 (μ3-S)2HgPPh3] (PF6)2 (3), [Pt2(PPh3)4(μ2-S) (μ3-S)HgPh]PF6 (4), and [Pt2(PPh3)4-(μ2-S) (μ3-S)AuPPh3]PF6 (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.title | Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ic011181o | - |
| dc.identifier.pmid | 12470082 | - |
| dc.identifier.scopus | eid_2-s2.0-0037121895 | - |
| dc.identifier.volume | 41 | - |
| dc.identifier.issue | 25 | - |
| dc.identifier.spage | 6838 | - |
| dc.identifier.epage | 6845 | - |
| dc.identifier.isi | WOS:000179797700038 | - |
| dc.identifier.issnl | 0020-1669 | - |