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- Publisher Website: 10.1016/S1381-1169(03)00308-X
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Article: Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3) 4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials
Title | Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3) 4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials |
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Authors | |
Keywords | Organic dihalides Organosulfur Sulfide Catalytic Electrospray mass spectrometric |
Issue Date | 2003 |
Citation | Journal of Molecular Catalysis A: Chemical, 2003, v. 204-205, p. 267-277 How to Cite? |
Abstract | Activity of [Pt2(μ-S)2(PPh3) 4] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′ -dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt2(μ-SC2H4S)(PPh 3)4][PF6]2 (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt2S2} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(η-S 2C4H8)(PPh3)]. © 2003 Elsevier Science B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/219484 |
ISSN | 2018 Impact Factor: 5.008 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chong, Siew Huay | - |
dc.contributor.author | Tjindrawan, Antonius | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:12Z | - |
dc.date.available | 2015-09-23T02:57:12Z | - |
dc.date.issued | 2003 | - |
dc.identifier.citation | Journal of Molecular Catalysis A: Chemical, 2003, v. 204-205, p. 267-277 | - |
dc.identifier.issn | 1381-1169 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219484 | - |
dc.description.abstract | Activity of [Pt2(μ-S)2(PPh3) 4] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′ -dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt2(μ-SC2H4S)(PPh 3)4][PF6]2 (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt2S2} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(η-S 2C4H8)(PPh3)]. © 2003 Elsevier Science B.V. All rights reserved. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Molecular Catalysis A: Chemical | - |
dc.subject | Organic dihalides | - |
dc.subject | Organosulfur | - |
dc.subject | Sulfide | - |
dc.subject | Catalytic | - |
dc.subject | Electrospray mass spectrometric | - |
dc.title | Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3) 4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S1381-1169(03)00308-X | - |
dc.identifier.scopus | eid_2-s2.0-1642393010 | - |
dc.identifier.volume | 204-205 | - |
dc.identifier.spage | 267 | - |
dc.identifier.epage | 277 | - |
dc.identifier.isi | WOS:000185387900026 | - |
dc.identifier.issnl | 1381-1169 | - |