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Article: Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene
Title | Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene |
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Authors | |
Issue Date | 1990 |
Citation | Polyhedron, 1990, v. 9, n. 18, p. 2305-2308 How to Cite? |
Abstract | A series of polynuclear heterometallic complexes (OC)5M(μ-dppf)M′(CO)5 (M, M′ = Cr, Mo, W; M ≠ M′) and (OC)5M(μ-dppf)Mn2(CO)9 (dppf = 1,1′-bis(diphenylphosphino) ferrocene) has been synthesized at room temperature based on the metallo-ligand M(CO)5(η1-dppf). The use of amine oxide as a decarbonylant preserves the integrity of the MnMn bond. The mixed metals are linked by a singly-bridging diphosphine group which does not perturb the two metal spheres. © 1990. |
Persistent Identifier | http://hdl.handle.net/10722/219520 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Hor, T. S A | - |
dc.contributor.author | Phang, L. T. | - |
dc.date.accessioned | 2015-09-23T02:57:17Z | - |
dc.date.available | 2015-09-23T02:57:17Z | - |
dc.date.issued | 1990 | - |
dc.identifier.citation | Polyhedron, 1990, v. 9, n. 18, p. 2305-2308 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219520 | - |
dc.description.abstract | A series of polynuclear heterometallic complexes (OC)5M(μ-dppf)M′(CO)5 (M, M′ = Cr, Mo, W; M ≠ M′) and (OC)5M(μ-dppf)Mn2(CO)9 (dppf = 1,1′-bis(diphenylphosphino) ferrocene) has been synthesized at room temperature based on the metallo-ligand M(CO)5(η1-dppf). The use of amine oxide as a decarbonylant preserves the integrity of the MnMn bond. The mixed metals are linked by a singly-bridging diphosphine group which does not perturb the two metal spheres. © 1990. | - |
dc.language | eng | - |
dc.relation.ispartof | Polyhedron | - |
dc.title | Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0277-5387(00)86958-2 | - |
dc.identifier.scopus | eid_2-s2.0-33748716780 | - |
dc.identifier.volume | 9 | - |
dc.identifier.issue | 18 | - |
dc.identifier.spage | 2305 | - |
dc.identifier.epage | 2308 | - |
dc.identifier.isi | WOS:A1990EA72800018 | - |
dc.identifier.issnl | 0277-5387 | - |