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- Publisher Website: 10.1016/0022-328X(94)88080-8
- Scopus: eid_2-s2.0-43949151053
- WOS: WOS:A1994NH85500016
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Article: 1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2
| Title | 1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2 |
|---|---|
| Authors | |
| Keywords | Gold Iron Phosphine Polymer Ferrocene Diphosphine |
| Issue Date | 1994 |
| Citation | Journal of Organometallic Chemistry, 1994, v. 469, n. 2, p. 253-261 How to Cite? |
| Abstract | Addition of molar equivalent of [Au2Cl2(μ-dppf)] to [Fe(C5H4PPh2)2] (dppf) gives an intermediate complex [AuCl(dppf)]x (1) which readily polymerises in solution to give [AuCl(dppf)]n.nCH2Cl2(2). X-ray diffraction analysis of 2 revealed a repeating unit of [AuCl(dppf)] propagating one-dimensionally along the c axis to give a zigzag chain. Complex 1 metathesises with AgNO3 to give [Au(NO3)(dppf)] x which reacts with HCO2Na to give [Au2(dppf-P,P′)2(μ-dppf)](NO3) 2.2H2O (3) as one of the products. The X-ray structure of 3 shows a centrosymmetric dimeric framework with two Au(dppf) chelates bridged by a dppf ligand. Both 2 and 3 show negligible inter- or intramolecular Au ⋯ Au interactions. © 1994. |
| Persistent Identifier | http://hdl.handle.net/10722/219572 |
| ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lai-Tee, Phang | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.contributor.author | Zhong-Yuan, Zhou | - |
| dc.contributor.author | Mak, Thomas C W | - |
| dc.date.accessioned | 2015-09-23T02:57:25Z | - |
| dc.date.available | 2015-09-23T02:57:25Z | - |
| dc.date.issued | 1994 | - |
| dc.identifier.citation | Journal of Organometallic Chemistry, 1994, v. 469, n. 2, p. 253-261 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219572 | - |
| dc.description.abstract | Addition of molar equivalent of [Au2Cl2(μ-dppf)] to [Fe(C5H4PPh2)2] (dppf) gives an intermediate complex [AuCl(dppf)]x (1) which readily polymerises in solution to give [AuCl(dppf)]n.nCH2Cl2(2). X-ray diffraction analysis of 2 revealed a repeating unit of [AuCl(dppf)] propagating one-dimensionally along the c axis to give a zigzag chain. Complex 1 metathesises with AgNO3 to give [Au(NO3)(dppf)] x which reacts with HCO2Na to give [Au2(dppf-P,P′)2(μ-dppf)](NO3) 2.2H2O (3) as one of the products. The X-ray structure of 3 shows a centrosymmetric dimeric framework with two Au(dppf) chelates bridged by a dppf ligand. Both 2 and 3 show negligible inter- or intramolecular Au ⋯ Au interactions. © 1994. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of Organometallic Chemistry | - |
| dc.subject | Gold | - |
| dc.subject | Iron | - |
| dc.subject | Phosphine | - |
| dc.subject | Polymer | - |
| dc.subject | Ferrocene | - |
| dc.subject | Diphosphine | - |
| dc.title | 1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2 | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0022-328X(94)88080-8 | - |
| dc.identifier.scopus | eid_2-s2.0-43949151053 | - |
| dc.identifier.volume | 469 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 253 | - |
| dc.identifier.epage | 261 | - |
| dc.identifier.isi | WOS:A1994NH85500016 | - |
| dc.identifier.issnl | 0022-328X | - |