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Article: Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates
| Title | Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates |
|---|---|
| Authors | |
| Issue Date | 1990 |
| Citation | Thermochimica Acta, 1990, v. 167, n. 1, p. 57-64 How to Cite? |
| Abstract | The solid state decomposition of Ni(CN)2(NH3)(G)n (or strictly, Ni(NH3)2Ni(CN)4· 2nG) where G = aniline, benzene and phenol, has been monitored by infrared spectroscopy, and thermogravimetric (TG) and differential scanning calorimetric analyses. The inclusion ratio, n, which can be conveniently obtained from the thermal profiles, follows the order C6H5NH2 /s C6H5OH /s C6H6. The step-wise degradation of these clathrates has been followed by TG and modelling experiments in Schlenk flasks. All the decompositional intermediates have been isolated and identified by TG, IR and microanalyses. © 1990. |
| Persistent Identifier | http://hdl.handle.net/10722/219574 |
| ISSN | 2023 Impact Factor: 3.1 2023 SCImago Journal Rankings: 0.572 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hor, T. S A | - |
| dc.contributor.author | Chan, H. S O | - |
| dc.contributor.author | Lee, H. K. | - |
| dc.contributor.author | Doshi, S. D. | - |
| dc.contributor.author | Leong, Y. P. | - |
| dc.contributor.author | Lian, W. T. | - |
| dc.contributor.author | Phang, L. T. | - |
| dc.contributor.author | Sim, M. M. | - |
| dc.contributor.author | Tan, M. M. | - |
| dc.date.accessioned | 2015-09-23T02:57:26Z | - |
| dc.date.available | 2015-09-23T02:57:26Z | - |
| dc.date.issued | 1990 | - |
| dc.identifier.citation | Thermochimica Acta, 1990, v. 167, n. 1, p. 57-64 | - |
| dc.identifier.issn | 0040-6031 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219574 | - |
| dc.description.abstract | The solid state decomposition of Ni(CN)2(NH3)(G)n (or strictly, Ni(NH3)2Ni(CN)4· 2nG) where G = aniline, benzene and phenol, has been monitored by infrared spectroscopy, and thermogravimetric (TG) and differential scanning calorimetric analyses. The inclusion ratio, n, which can be conveniently obtained from the thermal profiles, follows the order C6H5NH2 /s C6H5OH /s C6H6. The step-wise degradation of these clathrates has been followed by TG and modelling experiments in Schlenk flasks. All the decompositional intermediates have been isolated and identified by TG, IR and microanalyses. © 1990. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Thermochimica Acta | - |
| dc.title | Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0040-6031(90)80464-A | - |
| dc.identifier.scopus | eid_2-s2.0-44949290898 | - |
| dc.identifier.volume | 167 | - |
| dc.identifier.issue | 1 | - |
| dc.identifier.spage | 57 | - |
| dc.identifier.epage | 64 | - |
| dc.identifier.isi | WOS:A1990DZ87800005 | - |
| dc.identifier.issnl | 0040-6031 | - |