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- Publisher Website: 10.1039/b811493e
- Scopus: eid_2-s2.0-54349111698
- PMID: 18941657
- WOS: WOS:000260227000006
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Article: Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond
Title | Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond |
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Authors | |
Issue Date | 2008 |
Citation | Dalton Transactions, 2008, n. 42, p. 5708-5711 How to Cite? |
Abstract | Redox addition of the Pd-Pd bond in [Pd2Cl2(dppm) 2] across S-S or Se-Se bond in [Pt(X4- κ2X1,X4)(P-P)] (X = S, Se; P-P = dppe or 2 × PPh3; dppm = bis(diphenylphosphino)methane, dppe = bis(diphenylphosphino)ethane) leads to the isolation of [PtPd 2(μ3-X)2(P-P)(dppmX-κ2X, P4)2]2+ and represents an atom-economy process that converts chalcogen-rich complexes to heterometallic chalcogenide aggregates. Activation of the [PtX4] ring is achieved by tetrachalcogenide reduction and dual oxidation of palladium and phosphine. © 2008 The Royal Society of Chemistry. |
Persistent Identifier | http://hdl.handle.net/10722/219593 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.697 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Li, Jingqiu | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:28Z | - |
dc.date.available | 2015-09-23T02:57:28Z | - |
dc.date.issued | 2008 | - |
dc.identifier.citation | Dalton Transactions, 2008, n. 42, p. 5708-5711 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219593 | - |
dc.description.abstract | Redox addition of the Pd-Pd bond in [Pd2Cl2(dppm) 2] across S-S or Se-Se bond in [Pt(X4- κ2X1,X4)(P-P)] (X = S, Se; P-P = dppe or 2 × PPh3; dppm = bis(diphenylphosphino)methane, dppe = bis(diphenylphosphino)ethane) leads to the isolation of [PtPd 2(μ3-X)2(P-P)(dppmX-κ2X, P4)2]2+ and represents an atom-economy process that converts chalcogen-rich complexes to heterometallic chalcogenide aggregates. Activation of the [PtX4] ring is achieved by tetrachalcogenide reduction and dual oxidation of palladium and phosphine. © 2008 The Royal Society of Chemistry. | - |
dc.language | eng | - |
dc.relation.ispartof | Dalton Transactions | - |
dc.title | Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/b811493e | - |
dc.identifier.pmid | 18941657 | - |
dc.identifier.scopus | eid_2-s2.0-54349111698 | - |
dc.identifier.issue | 42 | - |
dc.identifier.spage | 5708 | - |
dc.identifier.epage | 5711 | - |
dc.identifier.eissn | 1477-9234 | - |
dc.identifier.isi | WOS:000260227000006 | - |
dc.identifier.issnl | 1477-9226 | - |