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Article: Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)

TitleUnexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
Authors
Yen, Swee KuanYoung, David J.Huynh, Han VinhKoh, Lip LinHor, T. S Andy
Issue Date2009
Citation
Chemical Communications, 2009, n. 44, p. 6831-6833 How to Cite?
DOI: http://dx.doi.org/10.1039/b914036k
AbstractThe reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219612
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133
ISI Accession Number ID
WOS:000271506700041

 

DC FieldValueLanguage
dc.contributor.authorYen, Swee Kuan-
dc.contributor.authorYoung, David J.-
dc.contributor.authorHuynh, Han Vinh-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:31Z-
dc.date.available2015-09-23T02:57:31Z-
dc.date.issued2009-
dc.identifier.citationChemical Communications, 2009, n. 44, p. 6831-6833-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/219612-
dc.description.abstractThe reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titleUnexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b914036k-
dc.identifier.pmid19885494-
dc.identifier.scopuseid_2-s2.0-70449563098-
dc.identifier.issue44-
dc.identifier.spage6831-
dc.identifier.epage6833-
dc.identifier.isiWOS:000271506700041-
dc.identifier.issnl1359-7345-

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