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- Publisher Website: 10.1039/c1dt10258c
- Scopus: eid_2-s2.0-80052095983
- PMID: 21494709
- WOS: WOS:000294475500027
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Article: Iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands in the cross-coupling of aryl Grignard with alkyl halides
| Title | Iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands in the cross-coupling of aryl Grignard with alkyl halides |
|---|---|
| Authors | |
| Issue Date | 2011 |
| Citation | Dalton Transactions, 2011, v. 40, n. 35, p. 8935-8940 How to Cite? |
| Abstract | Structurally distinctive Fe(ii) complexes with furan, thiophene and pyridine functionalized amine-pyrazolyl tripodal hybrid ligands have been synthesized and crystallographically characterized. The tether substituent at the central amine plays an active role in determining the coordination mode of the ligand and the metal geometry. All complexes are catalytically active towards cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides with β-hydrogen under ambient conditions. ESI-MS spectra analysis revealed the ligand-stabilised Fe(ii) and Mg(ii) species. © The Royal Society of Chemistry 2011. |
| Persistent Identifier | http://hdl.handle.net/10722/219655 |
| ISSN | 2021 Impact Factor: 4.569 2020 SCImago Journal Rankings: 0.980 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Xue, Fei | - |
| dc.contributor.author | Zhao, Jin | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2015-09-23T02:57:38Z | - |
| dc.date.available | 2015-09-23T02:57:38Z | - |
| dc.date.issued | 2011 | - |
| dc.identifier.citation | Dalton Transactions, 2011, v. 40, n. 35, p. 8935-8940 | - |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219655 | - |
| dc.description.abstract | Structurally distinctive Fe(ii) complexes with furan, thiophene and pyridine functionalized amine-pyrazolyl tripodal hybrid ligands have been synthesized and crystallographically characterized. The tether substituent at the central amine plays an active role in determining the coordination mode of the ligand and the metal geometry. All complexes are catalytically active towards cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides with β-hydrogen under ambient conditions. ESI-MS spectra analysis revealed the ligand-stabilised Fe(ii) and Mg(ii) species. © The Royal Society of Chemistry 2011. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Dalton Transactions | - |
| dc.title | Iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands in the cross-coupling of aryl Grignard with alkyl halides | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c1dt10258c | - |
| dc.identifier.pmid | 21494709 | - |
| dc.identifier.scopus | eid_2-s2.0-80052095983 | - |
| dc.identifier.volume | 40 | - |
| dc.identifier.issue | 35 | - |
| dc.identifier.spage | 8935 | - |
| dc.identifier.epage | 8940 | - |
| dc.identifier.eissn | 1477-9234 | - |
| dc.identifier.isi | WOS:000294475500027 | - |
| dc.identifier.issnl | 1477-9226 | - |