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- Publisher Website: 10.1021/om00028a010
- Scopus: eid_2-s2.0-0000892745
- WOS: WOS:A1993KX23300010
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Article: 5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]-
| Title | 5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]- |
|---|---|
| Authors | |
| Issue Date | 1993 |
| Citation | Organometallics, 1993, v. 12, n. 4, p. 1009-1011 How to Cite? |
| Abstract | [Mn3(CO)9(μ3-S)2] - has been isolated from the reaction between [Mn(CO)5]- and 5-substituted 1,3,4-oxathiazol-2-one (RCNSCO(O); R = phenyl, methyl, 3,5-dinitrophenyl) in THF. X-ray analysis revealed a D3h equilateral triangular cluster with three Mn(CO)3 units (Mn-Mn = 2.7680(16)-2.7918(13) Å) apically bicapped by two μ3-S ligands. The use of 1,3,4-oxathiazol-2-ones as a sulfur precursor allows facile nucleophilic attack from the carbonylmetalate and subsequent elimination of RCN and CO2. © 1993 American Chemical Society. |
| Persistent Identifier | http://hdl.handle.net/10722/219838 |
| ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Fang, Zhi Gang | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.contributor.author | Mok, K. F. | - |
| dc.contributor.author | Ng, Siu Choon | - |
| dc.contributor.author | Liu, Ling Kang | - |
| dc.contributor.author | Wen, Yuh Sheng | - |
| dc.date.accessioned | 2015-09-23T02:58:04Z | - |
| dc.date.available | 2015-09-23T02:58:04Z | - |
| dc.date.issued | 1993 | - |
| dc.identifier.citation | Organometallics, 1993, v. 12, n. 4, p. 1009-1011 | - |
| dc.identifier.issn | 0276-7333 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/219838 | - |
| dc.description.abstract | [Mn3(CO)9(μ3-S)2] - has been isolated from the reaction between [Mn(CO)5]- and 5-substituted 1,3,4-oxathiazol-2-one (RCNSCO(O); R = phenyl, methyl, 3,5-dinitrophenyl) in THF. X-ray analysis revealed a D3h equilateral triangular cluster with three Mn(CO)3 units (Mn-Mn = 2.7680(16)-2.7918(13) Å) apically bicapped by two μ3-S ligands. The use of 1,3,4-oxathiazol-2-ones as a sulfur precursor allows facile nucleophilic attack from the carbonylmetalate and subsequent elimination of RCN and CO2. © 1993 American Chemical Society. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Organometallics | - |
| dc.title | 5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]- | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/om00028a010 | - |
| dc.identifier.scopus | eid_2-s2.0-0000892745 | - |
| dc.identifier.volume | 12 | - |
| dc.identifier.issue | 4 | - |
| dc.identifier.spage | 1009 | - |
| dc.identifier.epage | 1011 | - |
| dc.identifier.isi | WOS:A1993KX23300010 | - |
| dc.identifier.issnl | 0276-7333 | - |