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Article: A binary catalyst system of a cationic Ru-CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide

TitleA binary catalyst system of a cationic Ru-CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide
Authors
Ng, Chee KoonWu, JieHor, T. S AndyLuo, He Kuan
Issue Date2016
Citation
Chemical Communications, 2016, v. 52, n. 79, p. 11842-11845 How to Cite?
DOI: http://dx.doi.org/10.1039/c6cc06278d
Abstract© The Royal Society of Chemistry 2016.Binary catalyst systems comprising a cationic Ru-CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO2 utilizing pinacolborane at r.t. and 1 atm CO2, with the combination of [Ru(CNCBn)(CO)2(H)][PF6] and KOCO2tBu producing formoxyborane in 76% yield. A bicyclic catalytic mechanism was proposed and discussed.
Persistent Identifierhttp://hdl.handle.net/10722/237536
ISSN
1359-7345
2021 Impact Factor: 6.065
2020 SCImago Journal Rankings: 1.837
ISI Accession Number ID
WOS:000384203700027
Errata
http://dx.doi.org/10.1039/C6CC90544G

 

DC FieldValueLanguage
dc.contributor.authorNg, Chee Koon-
dc.contributor.authorWu, Jie-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorLuo, He Kuan-
dc.date.accessioned2017-01-16T06:09:32Z-
dc.date.available2017-01-16T06:09:32Z-
dc.date.issued2016-
dc.identifier.citationChemical Communications, 2016, v. 52, n. 79, p. 11842-11845-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/237536-
dc.description.abstract© The Royal Society of Chemistry 2016.Binary catalyst systems comprising a cationic Ru-CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO2 utilizing pinacolborane at r.t. and 1 atm CO2, with the combination of [Ru(CNCBn)(CO)2(H)][PF6] and KOCO2tBu producing formoxyborane in 76% yield. A bicyclic catalytic mechanism was proposed and discussed.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titleA binary catalyst system of a cationic Ru-CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c6cc06278d-
dc.identifier.scopuseid_2-s2.0-84989229327-
dc.identifier.hkuros280163-
dc.identifier.hkuros285668-
dc.identifier.volume52-
dc.identifier.issue79-
dc.identifier.spage11842-
dc.identifier.epage11845-
dc.identifier.eissn1364-548X-
dc.identifier.isiWOS:000384203700027-
dc.relation.erratumdoi: 10.1039/C6CC90544G-
dc.customcontrol.immutablecsl 171103-
dc.identifier.issnl1359-7345-

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