File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 23-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)23-S)2] · 2CH2Cl2

TitleInter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd<inf>2</inf>Cl<inf>3</inf>(dppf) <inf>2</inf>(μ<inf>3</inf>-S)<inf>2</inf>] · 3CH<inf>2</inf>Cl <inf>2</inf> and [Ag<inf>2</inf>Pd<inf>2</inf>(NO<inf>3</inf>) <inf>2</inf>(dppf)<inf>2</inf>(μ<inf>3</inf>-S)<inf>2</inf>] · 2CH<inf>2</inf>Cl<inf>2</inf>
Authors
KeywordsStructure
Phosphine
Palladium
Metalloligand
Heterometallic
Ferrocenyl
Sulfide
Issue Date2005
Citation
Journal of Organometallic Chemistry, 2005, v. 690, n. 4, p. 990-997 How to Cite?
AbstractLewis acid/base addition between Pd2(dppf)2(μ-S) 2 and MXn [M = In(III), Ga(III), Tl(I), Pb(II), Sn(IV), Bi(III), Ag(I) and Au(I); X = halide or pseudohalide; dppf = 1,1′-bis(diphenylphosphino)ferrocene] gives rise to a range of neutral or cationic intermetallics aggregates with the {Pd2MS2} or {Pd2M2S2} core. Effectively Pd 2(dppf)2(μ-S)2 functions as a chelating or bridging dithio metalloligand. Two representative crystal structures, viz. [InPd2Cl3(dppf)2(μ3-S) 2] · 3CH2Cl2 and [Ag2Pd 2(NO3)2(dppf)2(μ3-S) 2] · 2CH2Cl2 are described and discussed. The former features an intermetallic {InPd2} triangle whereas the latter displays a heterometallic {Ag2Pd2} metal plane. Both of them are sustained and supported by capping sulfides without significant or direct metal-metal bonds. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/237563
ISSN
2020 Impact Factor: 2.369
2020 SCImago Journal Rankings: 0.484
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLi, Guangming-
dc.contributor.authorLam, Chi Keung-
dc.contributor.authorChien, Sheau W.-
dc.contributor.authorMak, Thomas C W-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:48Z-
dc.date.available2017-01-16T06:09:48Z-
dc.date.issued2005-
dc.identifier.citationJournal of Organometallic Chemistry, 2005, v. 690, n. 4, p. 990-997-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/237563-
dc.description.abstractLewis acid/base addition between Pd2(dppf)2(μ-S) 2 and MXn [M = In(III), Ga(III), Tl(I), Pb(II), Sn(IV), Bi(III), Ag(I) and Au(I); X = halide or pseudohalide; dppf = 1,1′-bis(diphenylphosphino)ferrocene] gives rise to a range of neutral or cationic intermetallics aggregates with the {Pd2MS2} or {Pd2M2S2} core. Effectively Pd 2(dppf)2(μ-S)2 functions as a chelating or bridging dithio metalloligand. Two representative crystal structures, viz. [InPd2Cl3(dppf)2(μ3-S) 2] · 3CH2Cl2 and [Ag2Pd 2(NO3)2(dppf)2(μ3-S) 2] · 2CH2Cl2 are described and discussed. The former features an intermetallic {InPd2} triangle whereas the latter displays a heterometallic {Ag2Pd2} metal plane. Both of them are sustained and supported by capping sulfides without significant or direct metal-metal bonds. © 2004 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectStructure-
dc.subjectPhosphine-
dc.subjectPalladium-
dc.subjectMetalloligand-
dc.subjectHeterometallic-
dc.subjectFerrocenyl-
dc.subjectSulfide-
dc.titleInter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd<inf>2</inf>Cl<inf>3</inf>(dppf) <inf>2</inf>(μ<inf>3</inf>-S)<inf>2</inf>] · 3CH<inf>2</inf>Cl <inf>2</inf> and [Ag<inf>2</inf>Pd<inf>2</inf>(NO<inf>3</inf>) <inf>2</inf>(dppf)<inf>2</inf>(μ<inf>3</inf>-S)<inf>2</inf>] · 2CH<inf>2</inf>Cl<inf>2</inf>-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2004.11.009-
dc.identifier.scopuseid_2-s2.0-13544262692-
dc.identifier.volume690-
dc.identifier.issue4-
dc.identifier.spage990-
dc.identifier.epage997-
dc.identifier.isiWOS:000227107500019-
dc.identifier.issnl0022-328X-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats