File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ic00085a060
- Scopus: eid_2-s2.0-33751157753
- WOS: WOS:A1994NE10200060
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: [PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4]
| Title | [PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4] |
|---|---|
| Authors | |
| Issue Date | 1994 |
| Citation | Inorganic Chemistry, 1994, v. 33, n. 7, p. 1572-1574 How to Cite? |
| Abstract | Lewis acid-base reactions between Pt2(mu-S)2(PPh3)4 (1) and GaCl3 and InCl3 give [(PPh3)4Pt2(mu3-S)2-[GaCl2][GaCl4] (2) and (PPh3)4Pt2(mu3-S)2InCl3 (3), respectively. The cation-anion pair 2 forms as a result of chloride transfer whereas 3 is a 1/1 adduct complex. Compound 3 (illustration) represents the first square-based pyramidal structure of a 5-coordinated adduct of InX3. |
| Persistent Identifier | http://hdl.handle.net/10722/237574 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Zhou, Meisheng | - |
| dc.contributor.author | Xu, Yan | - |
| dc.contributor.author | Lam, Choon Fui | - |
| dc.contributor.author | Leung, Pak Hing | - |
| dc.contributor.author | Koh, Lip Lin | - |
| dc.contributor.author | Mok, K. F. | - |
| dc.contributor.author | Andy Hor, T. S. | - |
| dc.date.accessioned | 2017-01-16T06:09:53Z | - |
| dc.date.available | 2017-01-16T06:09:53Z | - |
| dc.date.issued | 1994 | - |
| dc.identifier.citation | Inorganic Chemistry, 1994, v. 33, n. 7, p. 1572-1574 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/237574 | - |
| dc.description.abstract | Lewis acid-base reactions between Pt2(mu-S)2(PPh3)4 (1) and GaCl3 and InCl3 give [(PPh3)4Pt2(mu3-S)2-[GaCl2][GaCl4] (2) and (PPh3)4Pt2(mu3-S)2InCl3 (3), respectively. The cation-anion pair 2 forms as a result of chloride transfer whereas 3 is a 1/1 adduct complex. Compound 3 (illustration) represents the first square-based pyramidal structure of a 5-coordinated adduct of InX3. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.title | [PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4] | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ic00085a060 | - |
| dc.identifier.scopus | eid_2-s2.0-33751157753 | - |
| dc.identifier.volume | 33 | - |
| dc.identifier.issue | 7 | - |
| dc.identifier.spage | 1572 | - |
| dc.identifier.epage | 1574 | - |
| dc.identifier.isi | WOS:A1994NE10200060 | - |
| dc.identifier.issnl | 0020-1669 | - |