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- Scopus: eid_2-s2.0-41749117075
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Article: Fragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry
| Title | Fragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry |
|---|---|
| Authors | |
| Keywords | Sulfide complexes Crystal structure Electrospray mass spectrometry Thiolate complexes Platinum complexes Metalloligand |
| Issue Date | 2008 |
| Citation | Inorganica Chimica Acta, 2008, v. 361, n. 7, p. 1908-1914 How to Cite? |
| Abstract | The cationic monoalkylated derivatives of the well-known metalloligand [Pt2(μ-S)2(PPh3)4], viz. [Pt2(μ-S)(μ-SR)(PPh3)4]+ (R = n-Bu, CH2Ph) are themselves able to act as metalloligands towards the Ph3PAu+ and R′Hg+ (R′ = Ph or ferrocenyl) fragments, by reaction with Ph3PAuCl or R′HgCl, respectively. The resulting dicationic products [Pt2(μ-SR)(μ-SAuPPh3)(PPh3)4]2+ and [Pt2(μ-SR)(μ-SHgR′)(PPh3)4]2+ are readily isolated as their hexafluorophosphate salts, and have been fully characterised by spectroscopic techniques and an X-ray structure determination on [Pt2(μ-SR)(μ-SHgFc)(PPh3)4](PF6)2. © 2007 Elsevier B.V. All rights reserved. |
| Persistent Identifier | http://hdl.handle.net/10722/237580 |
| ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.386 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Henderson, William | - |
| dc.contributor.author | Nicholson, Brian K. | - |
| dc.contributor.author | Devoy, Sarah M. | - |
| dc.contributor.author | Andy Hor, T. S. | - |
| dc.date.accessioned | 2017-01-16T06:09:56Z | - |
| dc.date.available | 2017-01-16T06:09:56Z | - |
| dc.date.issued | 2008 | - |
| dc.identifier.citation | Inorganica Chimica Acta, 2008, v. 361, n. 7, p. 1908-1914 | - |
| dc.identifier.issn | 0020-1693 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/237580 | - |
| dc.description.abstract | The cationic monoalkylated derivatives of the well-known metalloligand [Pt2(μ-S)2(PPh3)4], viz. [Pt2(μ-S)(μ-SR)(PPh3)4]+ (R = n-Bu, CH2Ph) are themselves able to act as metalloligands towards the Ph3PAu+ and R′Hg+ (R′ = Ph or ferrocenyl) fragments, by reaction with Ph3PAuCl or R′HgCl, respectively. The resulting dicationic products [Pt2(μ-SR)(μ-SAuPPh3)(PPh3)4]2+ and [Pt2(μ-SR)(μ-SHgR′)(PPh3)4]2+ are readily isolated as their hexafluorophosphate salts, and have been fully characterised by spectroscopic techniques and an X-ray structure determination on [Pt2(μ-SR)(μ-SHgFc)(PPh3)4](PF6)2. © 2007 Elsevier B.V. All rights reserved. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganica Chimica Acta | - |
| dc.subject | Sulfide complexes | - |
| dc.subject | Crystal structure | - |
| dc.subject | Electrospray mass spectrometry | - |
| dc.subject | Thiolate complexes | - |
| dc.subject | Platinum complexes | - |
| dc.subject | Metalloligand | - |
| dc.title | Fragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/j.ica.2007.10.003 | - |
| dc.identifier.scopus | eid_2-s2.0-41749117075 | - |
| dc.identifier.volume | 361 | - |
| dc.identifier.issue | 7 | - |
| dc.identifier.spage | 1908 | - |
| dc.identifier.epage | 1914 | - |
| dc.identifier.isi | WOS:000256093500015 | - |
| dc.identifier.issnl | 0020-1693 | - |