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Article: Cobalt-catalyzed hydrogen desorption from the LiNH2–LiBH4 system

TitleCobalt-catalyzed hydrogen desorption from the LiNH2–LiBH4 system
Authors
Tang, Wan SiWu, GuotaoLiu, TaoWee, Andrew T SYong, Chaw KeongXiong, ZhitaoHor, Andy T SChen, Ping
Issue Date2008
Citation
Dalton Transactions, 2008, n. 18, p. 2395-2399 How to Cite?
DOI: http://dx.doi.org/10.1039/b719420j
AbstractA doping of 5 wt% CoCl2 considerably decreases the dehydrogenation temperature of a mixture of LiNH2 and LiBH 4. More that 8 wt% of hydrogen can be released at ca. 155 °C. X-Ray absorption near edge structure (XANES) spectroscopy indicated the formation of metallic Co after ball milling CoCl2 with LiNH 2 and LiBH4. Extended X-ray absorption fine structure (EXAFS) spectroscopy measurements revealed that Co particles have poor crystallinity and are finely dispersed in the sample, which could lead to a high catalytic efficiency. © The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/237581
ISSN
1477-9226
2023 Impact Factor: 3.5
2023 SCImago Journal Rankings: 0.697
ISI Accession Number ID
WOS:000255599000006

 

DC FieldValueLanguage
dc.contributor.authorTang, Wan Si-
dc.contributor.authorWu, Guotao-
dc.contributor.authorLiu, Tao-
dc.contributor.authorWee, Andrew T S-
dc.contributor.authorYong, Chaw Keong-
dc.contributor.authorXiong, Zhitao-
dc.contributor.authorHor, Andy T S-
dc.contributor.authorChen, Ping-
dc.date.accessioned2017-01-16T06:09:56Z-
dc.date.available2017-01-16T06:09:56Z-
dc.date.issued2008-
dc.identifier.citationDalton Transactions, 2008, n. 18, p. 2395-2399-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/237581-
dc.description.abstractA doping of 5 wt% CoCl2 considerably decreases the dehydrogenation temperature of a mixture of LiNH2 and LiBH 4. More that 8 wt% of hydrogen can be released at ca. 155 °C. X-Ray absorption near edge structure (XANES) spectroscopy indicated the formation of metallic Co after ball milling CoCl2 with LiNH 2 and LiBH4. Extended X-ray absorption fine structure (EXAFS) spectroscopy measurements revealed that Co particles have poor crystallinity and are finely dispersed in the sample, which could lead to a high catalytic efficiency. © The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleCobalt-catalyzed hydrogen desorption from the LiNH2–LiBH4 system-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b719420j-
dc.identifier.scopuseid_2-s2.0-43049123142-
dc.identifier.issue18-
dc.identifier.spage2395-
dc.identifier.epage2399-
dc.identifier.eissn1477-9234-
dc.identifier.isiWOS:000255599000006-
dc.identifier.issnl1477-9226-

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