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- Publisher Website: 10.1080/00958972.2014.911850
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Article: Synthesis, characterization, and catalytic activity of heterometallic ion-pair Ni/Mn and Ni/Zn complexes
Title | Synthesis, characterization, and catalytic activity of heterometallic ion-pair Ni/Mn and Ni/Zn complexes |
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Authors | |
Keywords | Cyanate Ion pair Heterometallic complex H/D exchange reaction Catalysis |
Issue Date | 2014 |
Citation | Journal of Coordination Chemistry, 2014, v. 67, n. 7, p. 1219-1235 How to Cite? |
Abstract | Two new heterometallic compounds, [Ni(bpy)3][Mn(NCO) 4]·H2O (1) and [Ni(phen)3] 2[Zn(NCO)4]2·4DMSO·H 2O (2) [bpy = 2,2′-bipyridine and phen = 1,10-phenanthroline], have been synthesized and characterized. The structures of 1 and 2 were solved by single-crystal X-ray diffraction analysis. The cationic moieties of [Ni(bpy)3]2+ in 1 and [Ni(phen)3]2+ in 2 show octahedral environments around Ni(II), whereas the anionic groups of [Mn(NCO)4]2- in 1 and [Zn(NCO)4]2- in 2 exhibit tetrahedral geometry around the Mn(II) and Zn(II), respectively. Both compounds are catalysts in the H/D exchange of salicylaldehyde in DMSO-d6 which takes place under mild conditions and short reaction time. © 2014 Taylor & Francis. |
Persistent Identifier | http://hdl.handle.net/10722/237610 |
ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.311 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Thuyweang, Nittaya | - |
dc.contributor.author | Koh, Lip Lin | - |
dc.contributor.author | Andy Hor, T. S. | - |
dc.contributor.author | Leelasubcharoen, Somying | - |
dc.date.accessioned | 2017-01-16T06:10:11Z | - |
dc.date.available | 2017-01-16T06:10:11Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Journal of Coordination Chemistry, 2014, v. 67, n. 7, p. 1219-1235 | - |
dc.identifier.issn | 0095-8972 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237610 | - |
dc.description.abstract | Two new heterometallic compounds, [Ni(bpy)3][Mn(NCO) 4]·H2O (1) and [Ni(phen)3] 2[Zn(NCO)4]2·4DMSO·H 2O (2) [bpy = 2,2′-bipyridine and phen = 1,10-phenanthroline], have been synthesized and characterized. The structures of 1 and 2 were solved by single-crystal X-ray diffraction analysis. The cationic moieties of [Ni(bpy)3]2+ in 1 and [Ni(phen)3]2+ in 2 show octahedral environments around Ni(II), whereas the anionic groups of [Mn(NCO)4]2- in 1 and [Zn(NCO)4]2- in 2 exhibit tetrahedral geometry around the Mn(II) and Zn(II), respectively. Both compounds are catalysts in the H/D exchange of salicylaldehyde in DMSO-d6 which takes place under mild conditions and short reaction time. © 2014 Taylor & Francis. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Coordination Chemistry | - |
dc.subject | Cyanate | - |
dc.subject | Ion pair | - |
dc.subject | Heterometallic complex | - |
dc.subject | H/D exchange reaction | - |
dc.subject | Catalysis | - |
dc.title | Synthesis, characterization, and catalytic activity of heterometallic ion-pair Ni/Mn and Ni/Zn complexes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1080/00958972.2014.911850 | - |
dc.identifier.scopus | eid_2-s2.0-84901642840 | - |
dc.identifier.volume | 67 | - |
dc.identifier.issue | 7 | - |
dc.identifier.spage | 1219 | - |
dc.identifier.epage | 1235 | - |
dc.identifier.eissn | 1029-0389 | - |
dc.identifier.isi | WOS:000337244100009 | - |
dc.identifier.issnl | 0095-8972 | - |