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Article: Transmetalation of a Dodecahedral Na9 Aggregate-Based Polymer: A Facile Route to Water Stable Cu(II) Coordination Networks

TitleTransmetalation of a Dodecahedral Na9 Aggregate-Based Polymer: A Facile Route to Water Stable Cu(II) Coordination Networks
Authors
Issue Date2014
Citation
Inorganic Chemistry, 2014, v. 53, n. 14, p. 7446-7454 How to Cite?
AbstractA variety of network structures have been prepared by transmetalation of a polymer {Na3[Na9(Cbdcp)6(H2O) 18]}n (1) (Cbdcp = N-(4-carboxybenzyl)-(3,5-dicarboxyl) pyridinium) containing dodecahedral Na9 aggregate secondary building units with Cu(II) by modulating the temperature, solvent, and pH. These complexes include a large, zwitterionic hexa-cuprometallocycle [Cu 6(Cbdcp)6(H2O)18] (2) formed in H2O at room temperature, two three-dimensional polymers [Cu 3(Cbdcp)2(OH)2(H2O) 2]n (3) and {[Cu3(Cbdcp)2(OH) 2]·2H2O}n (4) isolated from H 2O and DMF/H2O at 135 °C, and a mononuclear complex [Cu(HCbdcp)2(H2O)3]·H2O (5) from H2O at 100 °C and pH = 6. All the complexes are robust and water stable. The crystal framework of macrocycle 2 is stable up to 100 °C under vacuum and selectively adsorbs CO2. © 2014 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/237613
ISSN
2020 Impact Factor: 5.165
2020 SCImago Journal Rankings: 1.348
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChen, Jin Xiang-
dc.contributor.authorChen, Ming-
dc.contributor.authorDing, Ni Ni-
dc.contributor.authorChen, Wen Hua-
dc.contributor.authorZhang, Wen Hua-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorYoung, David J.-
dc.date.accessioned2017-01-16T06:10:12Z-
dc.date.available2017-01-16T06:10:12Z-
dc.date.issued2014-
dc.identifier.citationInorganic Chemistry, 2014, v. 53, n. 14, p. 7446-7454-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/237613-
dc.description.abstractA variety of network structures have been prepared by transmetalation of a polymer {Na3[Na9(Cbdcp)6(H2O) 18]}n (1) (Cbdcp = N-(4-carboxybenzyl)-(3,5-dicarboxyl) pyridinium) containing dodecahedral Na9 aggregate secondary building units with Cu(II) by modulating the temperature, solvent, and pH. These complexes include a large, zwitterionic hexa-cuprometallocycle [Cu 6(Cbdcp)6(H2O)18] (2) formed in H2O at room temperature, two three-dimensional polymers [Cu 3(Cbdcp)2(OH)2(H2O) 2]n (3) and {[Cu3(Cbdcp)2(OH) 2]·2H2O}n (4) isolated from H 2O and DMF/H2O at 135 °C, and a mononuclear complex [Cu(HCbdcp)2(H2O)3]·H2O (5) from H2O at 100 °C and pH = 6. All the complexes are robust and water stable. The crystal framework of macrocycle 2 is stable up to 100 °C under vacuum and selectively adsorbs CO2. © 2014 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleTransmetalation of a Dodecahedral Na9 Aggregate-Based Polymer: A Facile Route to Water Stable Cu(II) Coordination Networks-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic500789w-
dc.identifier.pmid24967909-
dc.identifier.scopuseid_2-s2.0-84904663793-
dc.identifier.volume53-
dc.identifier.issue14-
dc.identifier.spage7446-
dc.identifier.epage7454-
dc.identifier.eissn1520-510X-
dc.identifier.isiWOS:000339472000045-
dc.identifier.issnl0020-1669-

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