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Article: Dearomative Intramolecular (4+3) Cycloadditions of Arenes with Epoxy and Aziridinyl Enolsilanes

TitleDearomative Intramolecular (4+3) Cycloadditions of Arenes with Epoxy and Aziridinyl Enolsilanes
Authors
Keywordsarenes
cycloaddition
dearomatization
heterocycles
synthetic methods
Issue Date2017
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie (International Edition), 2017, v. 56, p. 8879-8882 How to Cite?
AbstractAn intramolecular (4+3) cycloaddition of epoxy and aziridinyl enolsilanes with benzene, naphthalene, and anthracene derivatives is reported. Highly functionalized polycyclic alcohols and amines are generated under relatively mild reaction conditions with yields up to 89 %. Optically enriched cycloadducts are obtained from cycloadditions of enantiomerically pure epoxides and aziridines.
Persistent Identifierhttp://hdl.handle.net/10722/243004
ISSN
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLING, J-
dc.contributor.authorLAM, YYS-
dc.contributor.authorLow, KH-
dc.contributor.authorChiu, P-
dc.date.accessioned2017-08-25T02:48:35Z-
dc.date.available2017-08-25T02:48:35Z-
dc.date.issued2017-
dc.identifier.citationAngewandte Chemie (International Edition), 2017, v. 56, p. 8879-8882-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/243004-
dc.description.abstractAn intramolecular (4+3) cycloaddition of epoxy and aziridinyl enolsilanes with benzene, naphthalene, and anthracene derivatives is reported. Highly functionalized polycyclic alcohols and amines are generated under relatively mild reaction conditions with yields up to 89 %. Optically enriched cycloadducts are obtained from cycloadditions of enantiomerically pure epoxides and aziridines.-
dc.languageeng-
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home-
dc.relation.ispartofAngewandte Chemie (International Edition)-
dc.rightspostprint: This is the accepted version of the following article: FULL CITE, which has been published in final form at [Link to final article]. Preprint This is the pre-peer reviewed version of the following article: FULL CITE, which has been published in final form at [Link to final article].-
dc.subjectarenes-
dc.subjectcycloaddition-
dc.subjectdearomatization-
dc.subjectheterocycles-
dc.subjectsynthetic methods-
dc.titleDearomative Intramolecular (4+3) Cycloadditions of Arenes with Epoxy and Aziridinyl Enolsilanes-
dc.typeArticle-
dc.identifier.emailLow, KH: khlow@hku.hk-
dc.identifier.emailChiu, P: pchiu@hku.hk-
dc.identifier.authorityChiu, P=rp00680-
dc.identifier.doi10.1002/anie.201704155-
dc.identifier.scopuseid_2-s2.0-85021013396-
dc.identifier.hkuros274426-
dc.identifier.volume56-
dc.identifier.spage8879-
dc.identifier.epage8882-
dc.identifier.isiWOS:000405308500051-
dc.publisher.placeGermany-
dc.identifier.issnl1433-7851-

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