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- Publisher Website: 10.1002/anie.201712249
- Scopus: eid_2-s2.0-85041229341
- PMID: 29266599
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Article: The Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes
Title | The Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes |
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Authors | |
Keywords | intermolecular interactions isocyanides living supramolecular polymerization MMLCT palladium |
Issue Date | 2018 |
Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093 How to Cite? |
Abstract | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Pincer PdII–isocyanide complexes are described that display intermolecular interactions and emissive3MMLCT excited states in aggregation state(s) at room temperature. The intermolecular PdII−PdIIand ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated by changing the counteranion and metal atom. The PdIIsupramolecular assemblies comprise two different aggregation forms with only one to be emissive. DFT/TDDFT calculations lend support to the MMLCT absorption and emission of these pincer PdII–isocyanide aggregates. |
Persistent Identifier | http://hdl.handle.net/10722/256835 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wan, Q | - |
dc.contributor.author | To, WP | - |
dc.contributor.author | Yang, C | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2018-07-24T08:58:04Z | - |
dc.date.available | 2018-07-24T08:58:04Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Angewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/256835 | - |
dc.description.abstract | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Pincer PdII–isocyanide complexes are described that display intermolecular interactions and emissive3MMLCT excited states in aggregation state(s) at room temperature. The intermolecular PdII−PdIIand ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated by changing the counteranion and metal atom. The PdIIsupramolecular assemblies comprise two different aggregation forms with only one to be emissive. DFT/TDDFT calculations lend support to the MMLCT absorption and emission of these pincer PdII–isocyanide aggregates. | - |
dc.language | eng | - |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | - |
dc.relation.ispartof | Angewandte Chemie (International Edition) | - |
dc.rights | This is the peer reviewed version of the following article: Angewandte Chemie (International Edition), 2018, v. 57 n. 12, p. 3089-3093, which has been published in final form at |https://doi.org/10.1002/anie.201712249].This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving: http://olabout.wiley.com/WileyCDA/Section/id-828039.html#terms | - |
dc.subject | intermolecular interactions | - |
dc.subject | isocyanides | - |
dc.subject | living supramolecular polymerization | - |
dc.subject | MMLCT | - |
dc.subject | palladium | - |
dc.title | The Metal-Metal-to-Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer PdII-Isocyanide Complexes | - |
dc.type | Article | - |
dc.identifier.email | To, WP: kevintwp@hku.hk | - |
dc.identifier.email | Yang, C: yangchen@HKUCC-COM.hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | To, WP=rp02410 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1002/anie.201712249 | - |
dc.identifier.pmid | 29266599 | - |
dc.identifier.scopus | eid_2-s2.0-85041229341 | - |
dc.identifier.hkuros | 287045 | - |
dc.identifier.volume | 57 | - |
dc.identifier.issue | 12 | - |
dc.identifier.spage | 3089 | - |
dc.identifier.epage | 3093 | - |
dc.identifier.eissn | 1521-3773 | - |
dc.identifier.isi | WOS:000426759900012 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 1433-7851 | - |