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Article: Metal-organic framework composites with luminescent pincer platinum(II) complexes:3MMLCT emission and photoinduced dehydrogenation catalysis
| Title | Metal-organic framework composites with luminescent pincer platinum(II) complexes:<sup>3</sup>MMLCT emission and photoinduced dehydrogenation catalysis |
|---|---|
| Authors | |
| Issue Date | 2018 |
| Citation | Chemical Science, 2018, v. 9, n. 8, p. 2357-2364 How to Cite? |
| Abstract | © 2018 The Royal Society of Chemistry. Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer (3MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a "solid solution" environment for easy access to3MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composites PtII@MOFs (1-4) with matrix-dependent monomers and oligomer emission properties were obtained. These PtII@MOFs are efficient catalysts for photoinduced dehydrogenation reactions. |
| Persistent Identifier | http://hdl.handle.net/10722/256838 |
| ISSN | 2022 Impact Factor: 8.4 2020 SCImago Journal Rankings: 3.687 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Sun, Chun Yi | - |
| dc.contributor.author | To, Wai Pong | - |
| dc.contributor.author | Hung, Faan Fung | - |
| dc.contributor.author | Wang, Xin Long | - |
| dc.contributor.author | Su, Zhong Min | - |
| dc.contributor.author | Che, Chi Ming | - |
| dc.date.accessioned | 2018-07-24T08:58:04Z | - |
| dc.date.available | 2018-07-24T08:58:04Z | - |
| dc.date.issued | 2018 | - |
| dc.identifier.citation | Chemical Science, 2018, v. 9, n. 8, p. 2357-2364 | - |
| dc.identifier.issn | 2041-6520 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/256838 | - |
| dc.description.abstract | © 2018 The Royal Society of Chemistry. Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer (3MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a "solid solution" environment for easy access to3MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composites PtII@MOFs (1-4) with matrix-dependent monomers and oligomer emission properties were obtained. These PtII@MOFs are efficient catalysts for photoinduced dehydrogenation reactions. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Chemical Science | - |
| dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
| dc.title | Metal-organic framework composites with luminescent pincer platinum(II) complexes:<sup>3</sup>MMLCT emission and photoinduced dehydrogenation catalysis | - |
| dc.type | Article | - |
| dc.description.nature | published_or_final_version | - |
| dc.identifier.doi | 10.1039/c7sc04528j | - |
| dc.identifier.scopus | eid_2-s2.0-85042621416 | - |
| dc.identifier.volume | 9 | - |
| dc.identifier.issue | 8 | - |
| dc.identifier.spage | 2357 | - |
| dc.identifier.epage | 2364 | - |
| dc.identifier.eissn | 2041-6539 | - |
| dc.identifier.isi | WOS:000427091500033 | - |
| dc.identifier.issnl | 2041-6520 | - |