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Article: A thermally derived and optimized structure from ZIF-8 with giant enhancement in CO2uptake

TitleA thermally derived and optimized structure from ZIF-8 with giant enhancement in CO<inf>2</inf>uptake
Authors
Gadipelli, SrinivasTravis, WillZhou, WeiGuo, Zhengxiao
Issue Date2014
Citation
Energy and Environmental Science, 2014, v. 7, n. 7, p. 2232-2238 How to Cite?
DOI: http://dx.doi.org/10.1039/c4ee01009d
AbstractWe report a new, simple and versatile method to obtain highly active MOF structures by carefully controlled post-synthesis thermal annealing. The active ZIF-8 structure shows highly enhanced CO2/N2selectivity and a stable cyclic CO2uptake of ≥1.5 mmol g-1at 1 bar and 25 °C with a heat of adsorption of ≥30 kJ mol-1, which is over 100% greater than ≈0.7 mmol g-1and ≈17 kJ mol-1, respectively of ZIF-8. © The Royal Society of Chemistry 2014.
Persistent Identifierhttp://hdl.handle.net/10722/262958
ISSN
1754-5692
2023 Impact Factor: 32.4
2023 SCImago Journal Rankings: 10.935
ISI Accession Number ID
WOS:000337977600012

 

DC FieldValueLanguage
dc.contributor.authorGadipelli, Srinivas-
dc.contributor.authorTravis, Will-
dc.contributor.authorZhou, Wei-
dc.contributor.authorGuo, Zhengxiao-
dc.date.accessioned2018-10-08T09:28:56Z-
dc.date.available2018-10-08T09:28:56Z-
dc.date.issued2014-
dc.identifier.citationEnergy and Environmental Science, 2014, v. 7, n. 7, p. 2232-2238-
dc.identifier.issn1754-5692-
dc.identifier.urihttp://hdl.handle.net/10722/262958-
dc.description.abstractWe report a new, simple and versatile method to obtain highly active MOF structures by carefully controlled post-synthesis thermal annealing. The active ZIF-8 structure shows highly enhanced CO2/N2selectivity and a stable cyclic CO2uptake of ≥1.5 mmol g-1at 1 bar and 25 °C with a heat of adsorption of ≥30 kJ mol-1, which is over 100% greater than ≈0.7 mmol g-1and ≈17 kJ mol-1, respectively of ZIF-8. © The Royal Society of Chemistry 2014.-
dc.languageeng-
dc.relation.ispartofEnergy and Environmental Science-
dc.titleA thermally derived and optimized structure from ZIF-8 with giant enhancement in CO<inf>2</inf>uptake-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c4ee01009d-
dc.identifier.scopuseid_2-s2.0-84902987773-
dc.identifier.volume7-
dc.identifier.issue7-
dc.identifier.spage2232-
dc.identifier.epage2238-
dc.identifier.eissn1754-5706-
dc.identifier.isiWOS:000337977600012-
dc.identifier.issnl1754-5692-

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