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- Publisher Website: 10.1002/anie.201811943
- Scopus: eid_2-s2.0-85057297830
- PMID: 30371013
- WOS: WOS:000454575500044
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Article: Counteranion- and Solvent-Mediated Chirality Transfer in the Supramolecular Polymerization of Luminescent Platinum(II) Complexes
Title | Counteranion- and Solvent-Mediated Chirality Transfer in the Supramolecular Polymerization of Luminescent Platinum(II) Complexes |
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Authors | |
Keywords | chirality transfer intermolecular interactions kinetic control pincer PtII complex supramolecular polymerization |
Issue Date | 2018 |
Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie (International Edition), 2018, v. 57 n.52, p. 17189-17193 How to Cite? |
Abstract | The chirality of supramolecular polymeric materials is subtly affected by a delicate balance among various non-covalent interactions, the details of which are inadequately understood. Now, a fine balance of intermolecular interactions, including closed-shell metal–metal, dispersive and electrostatic interactions, is used to direct the delicate orientation of monomeric building blocks, thereby achieving the successful preparation of different nanostructures with distinct supramolecular chirality. Moreover, kinetically trapped and thermodynamically stable aggregates were monitored over time in the supramolecular polymerization of cationic PtII complexes. The dynamic self-assembly process can be successfully controlled by modifying the counteranion and solvent composition. A chiral doping approach can also be used to induce the chirality of an achiral PtII complex at the supramolecular level. |
Persistent Identifier | http://hdl.handle.net/10722/269403 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wan, Q | - |
dc.contributor.author | Xiao, X | - |
dc.contributor.author | To, WP | - |
dc.contributor.author | Lu, W | - |
dc.contributor.author | Chen, Y | - |
dc.contributor.author | Low, KH | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2019-04-24T08:07:00Z | - |
dc.date.available | 2019-04-24T08:07:00Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Angewandte Chemie (International Edition), 2018, v. 57 n.52, p. 17189-17193 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/269403 | - |
dc.description.abstract | The chirality of supramolecular polymeric materials is subtly affected by a delicate balance among various non-covalent interactions, the details of which are inadequately understood. Now, a fine balance of intermolecular interactions, including closed-shell metal–metal, dispersive and electrostatic interactions, is used to direct the delicate orientation of monomeric building blocks, thereby achieving the successful preparation of different nanostructures with distinct supramolecular chirality. Moreover, kinetically trapped and thermodynamically stable aggregates were monitored over time in the supramolecular polymerization of cationic PtII complexes. The dynamic self-assembly process can be successfully controlled by modifying the counteranion and solvent composition. A chiral doping approach can also be used to induce the chirality of an achiral PtII complex at the supramolecular level. | - |
dc.language | eng | - |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | - |
dc.relation.ispartof | Angewandte Chemie (International Edition) | - |
dc.rights | Preprint This is the pre-peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article]. Authors are not required to remove preprints posted prior to acceptance of the submitted version. Postprint This is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving: http://olabout.wiley.com/WileyCDA/Section/id-828039.html#terms | - |
dc.subject | chirality transfer | - |
dc.subject | intermolecular interactions | - |
dc.subject | kinetic control | - |
dc.subject | pincer PtII complex | - |
dc.subject | supramolecular polymerization | - |
dc.title | Counteranion- and Solvent-Mediated Chirality Transfer in the Supramolecular Polymerization of Luminescent Platinum(II) Complexes | - |
dc.type | Article | - |
dc.identifier.email | To, WP: kevintwp@hku.hk | - |
dc.identifier.email | Low, KH: khlow@hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | To, WP=rp02410 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.201811943 | - |
dc.identifier.pmid | 30371013 | - |
dc.identifier.scopus | eid_2-s2.0-85057297830 | - |
dc.identifier.hkuros | 297299 | - |
dc.identifier.volume | 57 | - |
dc.identifier.issue | 52 | - |
dc.identifier.spage | 17189 | - |
dc.identifier.epage | 17193 | - |
dc.identifier.isi | WOS:000454575500044 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 1433-7851 | - |