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Article: An Effective [FeIII(TF4DMAP)Cl] Catalyst for C–H Bond Amination with Aryl and Alkyl Azides

TitleAn Effective [FeIII(TF4DMAP)Cl] Catalyst for C–H Bond Amination with Aryl and Alkyl Azides
Authors
Du, YXu, ZJZhou, CChe, CM
Issue Date2019
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html
Citation
Organic Letters, 2019, v. 21 n. 4, p. 895-899 How to Cite?
DOI: http://dx.doi.org/10.1021/acs.orglett.8b03765
Abstract[FeIII(TF4DMAP)Cl] can efficiently catalyze intermolecular sp3 C–H amination using aryl azides and intramolecular sp3 C–H amination of alkyl azides in moderate-to-high product yields. At catalyst loading down to 1 mol %, the reactions display high chemo- and regioselectivity with broad substrate scope and are effective for late-stage functionalization of complex natural/bioactive molecules.
Persistent Identifierhttp://hdl.handle.net/10722/269545
ISSN
1523-7060
2021 Impact Factor: 6.072
2020 SCImago Journal Rankings: 1.940
ISI Accession Number ID
WOS:000459366800010

 

DC FieldValueLanguage
dc.contributor.authorDu, Y-
dc.contributor.authorXu, ZJ-
dc.contributor.authorZhou, C-
dc.contributor.authorChe, CM-
dc.date.accessioned2019-04-24T08:09:52Z-
dc.date.available2019-04-24T08:09:52Z-
dc.date.issued2019-
dc.identifier.citationOrganic Letters, 2019, v. 21 n. 4, p. 895-899-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/269545-
dc.description.abstract[FeIII(TF4DMAP)Cl] can efficiently catalyze intermolecular sp3 C–H amination using aryl azides and intramolecular sp3 C–H amination of alkyl azides in moderate-to-high product yields. At catalyst loading down to 1 mol %, the reactions display high chemo- and regioselectivity with broad substrate scope and are effective for late-stage functionalization of complex natural/bioactive molecules.-
dc.languageeng-
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html-
dc.relation.ispartofOrganic Letters-
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.orglett.8b03765-
dc.titleAn Effective [FeIII(TF4DMAP)Cl] Catalyst for C–H Bond Amination with Aryl and Alkyl Azides-
dc.typeArticle-
dc.identifier.emailDu, Y: yidandu@HKUCC-COM.hku.hk-
dc.identifier.emailZhou, C: cyzhou@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityZhou, C=rp00843-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepostprint-
dc.identifier.doi10.1021/acs.orglett.8b03765-
dc.identifier.scopuseid_2-s2.0-85061250277-
dc.identifier.hkuros297304-
dc.identifier.volume21-
dc.identifier.issue4-
dc.identifier.spage895-
dc.identifier.epage899-
dc.identifier.isiWOS:000459366800010-
dc.publisher.placeUnited States-
dc.identifier.issnl1523-7052-

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