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Article: Selective C(sp3)–H Monoarylation Catalyzed by a Covalently Cross-Linked Reverse Micelle-Supported Palladium Catalyst

TitleSelective C(sp3)–H Monoarylation Catalyzed by a Covalently Cross-Linked Reverse Micelle-Supported Palladium Catalyst
Authors
Keywordsmicelles
C–H activation
palladium catalysis
monoarylation
supported catalysts
Issue Date2017
Citation
Advanced Synthesis and Catalysis, 2017, v. 359, n. 20, p. 3611-3617 How to Cite?
Abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim In this work, we illustrate the performance of a solvated micelle-supported ligand as a platform for coordination with palladium for C–H arylation. The micelle-supported ligand is one of the first applications of a micelle-supported ligand for C–H arylation, and provides a tunable support for future elaboration. The use of a spatially constrained system promoted selectivity trends influenced by both the sterics and electronics of the system, differing from the homogeneous catalyst, with high yields and selectivities. (Figure presented.).
Persistent Identifierhttp://hdl.handle.net/10722/276515
ISSN
2021 Impact Factor: 5.981
2020 SCImago Journal Rankings: 1.541
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHoyt, Caroline B.-
dc.contributor.authorLee, Li Chen-
dc.contributor.authorHe, Jian-
dc.contributor.authorYu, Jin Quan-
dc.contributor.authorJones, Christopher W.-
dc.date.accessioned2019-09-18T08:33:51Z-
dc.date.available2019-09-18T08:33:51Z-
dc.date.issued2017-
dc.identifier.citationAdvanced Synthesis and Catalysis, 2017, v. 359, n. 20, p. 3611-3617-
dc.identifier.issn1615-4150-
dc.identifier.urihttp://hdl.handle.net/10722/276515-
dc.description.abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim In this work, we illustrate the performance of a solvated micelle-supported ligand as a platform for coordination with palladium for C–H arylation. The micelle-supported ligand is one of the first applications of a micelle-supported ligand for C–H arylation, and provides a tunable support for future elaboration. The use of a spatially constrained system promoted selectivity trends influenced by both the sterics and electronics of the system, differing from the homogeneous catalyst, with high yields and selectivities. (Figure presented.).-
dc.languageeng-
dc.relation.ispartofAdvanced Synthesis and Catalysis-
dc.subjectmicelles-
dc.subjectC–H activation-
dc.subjectpalladium catalysis-
dc.subjectmonoarylation-
dc.subjectsupported catalysts-
dc.titleSelective C(sp3)–H Monoarylation Catalyzed by a Covalently Cross-Linked Reverse Micelle-Supported Palladium Catalyst-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/adsc.201700707-
dc.identifier.scopuseid_2-s2.0-85032361958-
dc.identifier.volume359-
dc.identifier.issue20-
dc.identifier.spage3611-
dc.identifier.epage3617-
dc.identifier.eissn1615-4169-
dc.identifier.isiWOS:000413673600024-
dc.identifier.issnl1615-4150-

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