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- Publisher Website: 10.1021/jacs.7b10026
- Scopus: eid_2-s2.0-85037542252
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Article: On-Surface Cyclization of ortho-Dihalotetracenes to Four- and Six-Membered Rings
Title | On-Surface Cyclization of ortho-Dihalotetracenes to Four- and Six-Membered Rings |
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Authors | |
Issue Date | 2017 |
Citation | Journal of the American Chemical Society, 2017, v. 139, n. 48, p. 17617-17623 How to Cite? |
Abstract | © 2017 American Chemical Society. We report on the surface-catalyzed formal [2+2] and [2+2+2] cycloadditions of ortho-activated tetracene species on a Ag(111) substrate under ultrahigh vacuum conditions. Three different products are obtained: tetracene dimers, trimers, and tetramers. The former results from the formation of a four-membered ring while the other two arise from cyclization into six-membered rings. These on-surface reactions have been monitored by scanning tunneling microscopy and rationalized by density functional theory calculations. Our approach, based on the reaction of ortho-dihalo precursor monomers via formal cycloadditions, establishes an additional method for the highly active field of on-surface synthesis and enables the development of novel 1D and 2D covalent carbon nanostructures. |
Persistent Identifier | http://hdl.handle.net/10722/276567 |
ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Sánchez-Sánchez, Carlos | - |
dc.contributor.author | Nicolaï, Adrien | - |
dc.contributor.author | Rossel, Frédéric | - |
dc.contributor.author | Cai, Jinming | - |
dc.contributor.author | Liu, Junzhi | - |
dc.contributor.author | Feng, Xinliang | - |
dc.contributor.author | Müllen, Klaus | - |
dc.contributor.author | Ruffieux, Pascal | - |
dc.contributor.author | Fasel, Roman | - |
dc.contributor.author | Meunier, Vincent | - |
dc.date.accessioned | 2019-09-18T08:34:00Z | - |
dc.date.available | 2019-09-18T08:34:00Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2017, v. 139, n. 48, p. 17617-17623 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10722/276567 | - |
dc.description.abstract | © 2017 American Chemical Society. We report on the surface-catalyzed formal [2+2] and [2+2+2] cycloadditions of ortho-activated tetracene species on a Ag(111) substrate under ultrahigh vacuum conditions. Three different products are obtained: tetracene dimers, trimers, and tetramers. The former results from the formation of a four-membered ring while the other two arise from cyclization into six-membered rings. These on-surface reactions have been monitored by scanning tunneling microscopy and rationalized by density functional theory calculations. Our approach, based on the reaction of ortho-dihalo precursor monomers via formal cycloadditions, establishes an additional method for the highly active field of on-surface synthesis and enables the development of novel 1D and 2D covalent carbon nanostructures. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of the American Chemical Society | - |
dc.title | On-Surface Cyclization of ortho-Dihalotetracenes to Four- and Six-Membered Rings | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/jacs.7b10026 | - |
dc.identifier.scopus | eid_2-s2.0-85037542252 | - |
dc.identifier.volume | 139 | - |
dc.identifier.issue | 48 | - |
dc.identifier.spage | 17617 | - |
dc.identifier.epage | 17623 | - |
dc.identifier.eissn | 1520-5126 | - |
dc.identifier.isi | WOS:000417669000059 | - |
dc.identifier.issnl | 0002-7863 | - |