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- Publisher Website: 10.1021/ja400648w
- Scopus: eid_2-s2.0-84874860520
- PMID: 23406445
- WOS: WOS:000315936700022
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Article: Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds
| Title | Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds |
|---|---|
| Authors | |
| Issue Date | 2013 |
| Citation | Journal of the American Chemical Society, 2013, v. 135, n. 9, p. 3387-3390 How to Cite? |
| Abstract | The alkynylation of β-C(sp3)-H bonds in aliphatic amides with alkynyl halides has been enabled using Pd(0)/N-heterocyclic carbene (NHC) and Pd(0)/phosphine (PR3) catalysts. This is the first example of utilizing [AlkynylPd(II)Ln] complexes to activate C(sp3)-H bonds. © 2013 American Chemical Society. |
| Persistent Identifier | http://hdl.handle.net/10722/276673 |
| ISSN | 2021 Impact Factor: 16.383 2020 SCImago Journal Rankings: 7.115 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | He, Jian | - |
| dc.contributor.author | Wasa, Masayuki | - |
| dc.contributor.author | Chan, Kelvin S L | - |
| dc.contributor.author | Yu, Jin Quan | - |
| dc.date.accessioned | 2019-09-18T08:34:19Z | - |
| dc.date.available | 2019-09-18T08:34:19Z | - |
| dc.date.issued | 2013 | - |
| dc.identifier.citation | Journal of the American Chemical Society, 2013, v. 135, n. 9, p. 3387-3390 | - |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/276673 | - |
| dc.description.abstract | The alkynylation of β-C(sp3)-H bonds in aliphatic amides with alkynyl halides has been enabled using Pd(0)/N-heterocyclic carbene (NHC) and Pd(0)/phosphine (PR3) catalysts. This is the first example of utilizing [AlkynylPd(II)Ln] complexes to activate C(sp3)-H bonds. © 2013 American Chemical Society. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the American Chemical Society | - |
| dc.title | Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ja400648w | - |
| dc.identifier.pmid | 23406445 | - |
| dc.identifier.scopus | eid_2-s2.0-84874860520 | - |
| dc.identifier.volume | 135 | - |
| dc.identifier.issue | 9 | - |
| dc.identifier.spage | 3387 | - |
| dc.identifier.epage | 3390 | - |
| dc.identifier.eissn | 1520-5126 | - |
| dc.identifier.isi | WOS:000315936700022 | - |
| dc.identifier.issnl | 0002-7863 | - |