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Article: Ligand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines

TitleLigand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines
Authors
Keywordsamines
amination
rhodium
quinolines
ligand design
Issue Date2017
Citation
Angewandte Chemie - International Edition, 2017, v. 56, n. 26, p. 7449-7453 How to Cite?
Abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Ligand development for rhodium(III)-catalyzed C−H activation reactions has largely been limited to cyclopentadienyl (Cp) based scaffolds. 2-Methylquinoline has now been identified as a feasible ligand that can coordinate to the metal center of Cp*RhCl to accelerate the cleavage of the C−H bond of N-pentafluorophenylbenzamides, providing a new structural lead for ligand design. The compatibility of this reaction with secondary free amines and anilines also overcomes the limitations of palladium(II)-catalyzed C−H amination reactions.
Persistent Identifierhttp://hdl.handle.net/10722/277077
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWang, Huai Wei-
dc.contributor.authorLu, Yi-
dc.contributor.authorZhang, Bing-
dc.contributor.authorHe, Jian-
dc.contributor.authorXu, Hua Jin-
dc.contributor.authorKang, Yan Shang-
dc.contributor.authorSun, Wei Yin-
dc.contributor.authorYu, Jin Quan-
dc.date.accessioned2019-09-18T08:35:32Z-
dc.date.available2019-09-18T08:35:32Z-
dc.date.issued2017-
dc.identifier.citationAngewandte Chemie - International Edition, 2017, v. 56, n. 26, p. 7449-7453-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/277077-
dc.description.abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Ligand development for rhodium(III)-catalyzed C−H activation reactions has largely been limited to cyclopentadienyl (Cp) based scaffolds. 2-Methylquinoline has now been identified as a feasible ligand that can coordinate to the metal center of Cp*RhCl to accelerate the cleavage of the C−H bond of N-pentafluorophenylbenzamides, providing a new structural lead for ligand design. The compatibility of this reaction with secondary free amines and anilines also overcomes the limitations of palladium(II)-catalyzed C−H amination reactions.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectamines-
dc.subjectamination-
dc.subjectrhodium-
dc.subjectquinolines-
dc.subjectligand design-
dc.titleLigand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201703300-
dc.identifier.pmid28500664-
dc.identifier.scopuseid_2-s2.0-85020398937-
dc.identifier.volume56-
dc.identifier.issue26-
dc.identifier.spage7449-
dc.identifier.epage7453-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000403017000018-
dc.identifier.issnl1433-7851-

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