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- Publisher Website: 10.1021/acs.chemrev.6b00622
- Scopus: eid_2-s2.0-85024091332
- PMID: 28697604
- WOS: WOS:000405642800009
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Article: Palladium-Catalyzed Transformations of Alkyl C-H Bonds
Title | Palladium-Catalyzed Transformations of Alkyl C-H Bonds |
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Authors | |
Issue Date | 2017 |
Citation | Chemical Reviews, 2017, v. 117, n. 13, p. 8754-8786 How to Cite? |
Abstract | © 2016 American Chemical Society. This Review summarizes the advancements in Pd-catalyzed C(sp3)-H activation via various redox manifolds, including Pd(0)/Pd(II), Pd(II)/Pd(IV), and Pd(II)/Pd(0). While few examples have been reported in the activation of alkane C-H bonds, many C(sp3)-H activation/C-C and C-heteroatom bond forming reactions have been developed by the use of directing group strategies to control regioselectivity and build structural patterns for synthetic chemistry. A number of mono- and bidentate ligands have also proven to be effective for accelerating C(sp3)-H activation directed by weakly coordinating auxiliaries, which provides great opportunities to control reactivity and selectivity (including enantioselectivity) in Pd-catalyzed C-H functionalization reactions. |
Persistent Identifier | http://hdl.handle.net/10722/277083 |
ISSN | 2023 Impact Factor: 51.4 2023 SCImago Journal Rankings: 17.828 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | He, Jian | - |
dc.contributor.author | Wasa, Masayuki | - |
dc.contributor.author | Chan, Kelvin S.L. | - |
dc.contributor.author | Shao, Qian | - |
dc.contributor.author | Yu, Jin Quan | - |
dc.date.accessioned | 2019-09-18T08:35:33Z | - |
dc.date.available | 2019-09-18T08:35:33Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Chemical Reviews, 2017, v. 117, n. 13, p. 8754-8786 | - |
dc.identifier.issn | 0009-2665 | - |
dc.identifier.uri | http://hdl.handle.net/10722/277083 | - |
dc.description.abstract | © 2016 American Chemical Society. This Review summarizes the advancements in Pd-catalyzed C(sp3)-H activation via various redox manifolds, including Pd(0)/Pd(II), Pd(II)/Pd(IV), and Pd(II)/Pd(0). While few examples have been reported in the activation of alkane C-H bonds, many C(sp3)-H activation/C-C and C-heteroatom bond forming reactions have been developed by the use of directing group strategies to control regioselectivity and build structural patterns for synthetic chemistry. A number of mono- and bidentate ligands have also proven to be effective for accelerating C(sp3)-H activation directed by weakly coordinating auxiliaries, which provides great opportunities to control reactivity and selectivity (including enantioselectivity) in Pd-catalyzed C-H functionalization reactions. | - |
dc.language | eng | - |
dc.relation.ispartof | Chemical Reviews | - |
dc.title | Palladium-Catalyzed Transformations of Alkyl C-H Bonds | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/acs.chemrev.6b00622 | - |
dc.identifier.pmid | 28697604 | - |
dc.identifier.scopus | eid_2-s2.0-85024091332 | - |
dc.identifier.volume | 117 | - |
dc.identifier.issue | 13 | - |
dc.identifier.spage | 8754 | - |
dc.identifier.epage | 8786 | - |
dc.identifier.eissn | 1520-6890 | - |
dc.identifier.isi | WOS:000405642800009 | - |
dc.identifier.issnl | 0009-2665 | - |