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Article: The first crystallographically characterised ruthenium(vi) alkylimido porphyrin competent for aerobic epoxidation and hydrogen atom abstraction

TitleThe first crystallographically characterised ruthenium(vi) alkylimido porphyrin competent for aerobic epoxidation and hydrogen atom abstraction
Authors
Shing, KPWan, QChang, XChe, CM
Keywordscatalysis
chemical reaction
intermolecular amino oxyarylation
spectroscopy
Issue Date2020
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2020, v. 56 n. 32, p. 4428-4431 How to Cite?
DOI: http://dx.doi.org/10.1039/C9CC09972G
AbstractThe syntheses of [RuVI(Por)(NAd)(O)] and [RuVI(2,6-F2-TPP)(NAd)2] have been described. [RuVI(2,6-F2-TPP)(NAd)(O)] capable of catalysing aerobic epoxidation of alkenes has been characterised by X-ray crystallography with Ru[double bond, length as m-dash]NAd and Ru[double bond, length as m-dash]O bond distances being 1.778(5) Å and 1.760(4) Å (∠O–Ru–NAd: 174.37(19)°), respectively. Its first reduction potential is 740 mV cathodically shifted from that of [RuVI(2,6-F2-TPP)(O)2].
Persistent Identifierhttp://hdl.handle.net/10722/282895
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133
ISI Accession Number ID
WOS:000529215100006

 

DC FieldValueLanguage
dc.contributor.authorShing, KP-
dc.contributor.authorWan, Q-
dc.contributor.authorChang, X-
dc.contributor.authorChe, CM-
dc.date.accessioned2020-06-05T06:22:49Z-
dc.date.available2020-06-05T06:22:49Z-
dc.date.issued2020-
dc.identifier.citationChemical Communications, 2020, v. 56 n. 32, p. 4428-4431-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/282895-
dc.description.abstractThe syntheses of [RuVI(Por)(NAd)(O)] and [RuVI(2,6-F2-TPP)(NAd)2] have been described. [RuVI(2,6-F2-TPP)(NAd)(O)] capable of catalysing aerobic epoxidation of alkenes has been characterised by X-ray crystallography with Ru[double bond, length as m-dash]NAd and Ru[double bond, length as m-dash]O bond distances being 1.778(5) Å and 1.760(4) Å (∠O–Ru–NAd: 174.37(19)°), respectively. Its first reduction potential is 740 mV cathodically shifted from that of [RuVI(2,6-F2-TPP)(O)2].-
dc.languageeng-
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp-
dc.relation.ispartofChemical Communications-
dc.subjectcatalysis-
dc.subjectchemical reaction-
dc.subjectintermolecular amino oxyarylation-
dc.subjectspectroscopy-
dc.titleThe first crystallographically characterised ruthenium(vi) alkylimido porphyrin competent for aerobic epoxidation and hydrogen atom abstraction-
dc.typeArticle-
dc.identifier.emailShing, KP: panshing@hku.hk-
dc.identifier.emailWan, Q: wendyqyw@hku.hk-
dc.identifier.emailChang, X: xychang@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C9CC09972G-
dc.identifier.pmid32195498-
dc.identifier.scopuseid_2-s2.0-85083913073-
dc.identifier.hkuros310322-
dc.identifier.volume56-
dc.identifier.issue32-
dc.identifier.spage4428-
dc.identifier.epage4431-
dc.identifier.isiWOS:000529215100006-
dc.publisher.placeUnited Kingdom-
dc.identifier.issnl1359-7345-

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