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- Publisher Website: 10.1002/anie.202009255
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Article: Total Synthesis of Cryptotrione
| Title | Total Synthesis of Cryptotrione |
|---|---|
| Authors | |
| Keywords | total synthesis cryptotrione Enyne isomerization Cyclization |
| Issue Date | 2020 |
| Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773 |
| Citation | Angewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933 How to Cite? |
| Abstract | The first total synthesis of cryptotrione ( 1 ) has been achieved through substrate‐controlled diastereoselective construction of the bicyclo[3.1.0]hexene framework via platinum‐catalyzed enyne cycloisomerization, Lewis‐acid induced polyene cyclization to construct the abietane type tricyclic diterpene skeleton, as well as diastereo‐divergent conjugate addition to generate the tertiary carbon center on the side chain. |
| Persistent Identifier | http://hdl.handle.net/10722/284791 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wong, HNC | - |
| dc.contributor.author | Lyu, MY | - |
| dc.contributor.author | Zhong, Z | - |
| dc.contributor.author | Lo, VKY | - |
| dc.contributor.author | Peng, XS | - |
| dc.date.accessioned | 2020-08-07T09:02:40Z | - |
| dc.date.available | 2020-08-07T09:02:40Z | - |
| dc.date.issued | 2020 | - |
| dc.identifier.citation | Angewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/284791 | - |
| dc.description.abstract | The first total synthesis of cryptotrione ( 1 ) has been achieved through substrate‐controlled diastereoselective construction of the bicyclo[3.1.0]hexene framework via platinum‐catalyzed enyne cycloisomerization, Lewis‐acid induced polyene cyclization to construct the abietane type tricyclic diterpene skeleton, as well as diastereo‐divergent conjugate addition to generate the tertiary carbon center on the side chain. | - |
| dc.language | eng | - |
| dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773 | - |
| dc.relation.ispartof | Angewandte Chemie (International Edition) | - |
| dc.rights | This is the peer reviewed version of the following article: Angewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933, which has been published in final form at https://doi.org/10.1002/anie.202009255. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | - |
| dc.subject | total synthesis | - |
| dc.subject | cryptotrione | - |
| dc.subject | Enyne | - |
| dc.subject | isomerization | - |
| dc.subject | Cyclization | - |
| dc.title | Total Synthesis of Cryptotrione | - |
| dc.type | Article | - |
| dc.identifier.email | Lo, VKY: vkylo@hku.hk | - |
| dc.description.nature | postprint | - |
| dc.identifier.doi | 10.1002/anie.202009255 | - |
| dc.identifier.scopus | eid_2-s2.0-85090065372 | - |
| dc.identifier.hkuros | 311891 | - |
| dc.identifier.volume | 59 | - |
| dc.identifier.issue | 45 | - |
| dc.identifier.spage | 19929 | - |
| dc.identifier.epage | 19933 | - |
| dc.identifier.isi | WOS:000565160000001 | - |
| dc.publisher.place | Germany | - |
| dc.identifier.issnl | 1433-7851 | - |