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Article: Total Synthesis of Cryptotrione

TitleTotal Synthesis of Cryptotrione
Authors
Keywordstotal synthesis
cryptotrione
Enyne
isomerization
Cyclization
Issue Date2020
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773
Citation
Angewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933 How to Cite?
AbstractThe first total synthesis of cryptotrione ( 1 ) has been achieved through substrate‐controlled diastereoselective construction of the bicyclo[3.1.0]hexene framework via platinum‐catalyzed enyne cycloisomerization, Lewis‐acid induced polyene cyclization to construct the abietane type tricyclic diterpene skeleton, as well as diastereo‐divergent conjugate addition to generate the tertiary carbon center on the side chain.
Persistent Identifierhttp://hdl.handle.net/10722/284791
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWong, HNC-
dc.contributor.authorLyu, MY-
dc.contributor.authorZhong, Z-
dc.contributor.authorLo, VKY-
dc.contributor.authorPeng, XS-
dc.date.accessioned2020-08-07T09:02:40Z-
dc.date.available2020-08-07T09:02:40Z-
dc.date.issued2020-
dc.identifier.citationAngewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/284791-
dc.description.abstractThe first total synthesis of cryptotrione ( 1 ) has been achieved through substrate‐controlled diastereoselective construction of the bicyclo[3.1.0]hexene framework via platinum‐catalyzed enyne cycloisomerization, Lewis‐acid induced polyene cyclization to construct the abietane type tricyclic diterpene skeleton, as well as diastereo‐divergent conjugate addition to generate the tertiary carbon center on the side chain.-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773-
dc.relation.ispartofAngewandte Chemie (International Edition)-
dc.rightsThis is the peer reviewed version of the following article: Angewandte Chemie (International Edition), 2020, v. 59 n. 45, p. 19929-19933, which has been published in final form at https://doi.org/10.1002/anie.202009255. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjecttotal synthesis-
dc.subjectcryptotrione-
dc.subjectEnyne-
dc.subjectisomerization-
dc.subjectCyclization-
dc.titleTotal Synthesis of Cryptotrione-
dc.typeArticle-
dc.identifier.emailLo, VKY: vkylo@hku.hk-
dc.description.naturepostprint-
dc.identifier.doi10.1002/anie.202009255-
dc.identifier.scopuseid_2-s2.0-85090065372-
dc.identifier.hkuros311891-
dc.identifier.volume59-
dc.identifier.issue45-
dc.identifier.spage19929-
dc.identifier.epage19933-
dc.identifier.isiWOS:000565160000001-
dc.publisher.placeGermany-
dc.identifier.issnl1433-7851-

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