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Article: Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes

TitleEnergy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes
Authors
Keywordsenergy transfer
antenna probes
luminescence
ab initio calculations
resonant crossing
Issue Date2017
Citation
Angewandte Chemie - International Edition, 2017, v. 56, n. 27, p. 7986-7990 How to Cite?
Abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum-chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet–quintet intersystem crossing on the basis of spin–orbit coupling among the sublevels of the involved states.
Persistent Identifierhttp://hdl.handle.net/10722/289066
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorZhang, Qiangqiang-
dc.contributor.authorWu, Liangliang-
dc.contributor.authorCao, Xiaoyan-
dc.contributor.authorChen, Xuebo-
dc.contributor.authorFang, Weihai-
dc.contributor.authorDolg, Michael-
dc.date.accessioned2020-10-12T08:06:35Z-
dc.date.available2020-10-12T08:06:35Z-
dc.date.issued2017-
dc.identifier.citationAngewandte Chemie - International Edition, 2017, v. 56, n. 27, p. 7986-7990-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/289066-
dc.description.abstract© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum-chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet–quintet intersystem crossing on the basis of spin–orbit coupling among the sublevels of the involved states.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectenergy transfer-
dc.subjectantenna probes-
dc.subjectluminescence-
dc.subjectab initio calculations-
dc.subjectresonant crossing-
dc.titleEnergy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201701575-
dc.identifier.pmid28374566-
dc.identifier.scopuseid_2-s2.0-85017346394-
dc.identifier.volume56-
dc.identifier.issue27-
dc.identifier.spage7986-
dc.identifier.epage7990-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000403839000056-
dc.identifier.issnl1433-7851-

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