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- Publisher Website: 10.1002/anie.201701575
- Scopus: eid_2-s2.0-85017346394
- PMID: 28374566
- WOS: WOS:000403839000056
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Article: Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes
Title | Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes |
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Authors | |
Keywords | energy transfer antenna probes luminescence ab initio calculations resonant crossing |
Issue Date | 2017 |
Citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 27, p. 7986-7990 How to Cite? |
Abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum-chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet–quintet intersystem crossing on the basis of spin–orbit coupling among the sublevels of the involved states. |
Persistent Identifier | http://hdl.handle.net/10722/289066 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Zhang, Qiangqiang | - |
dc.contributor.author | Wu, Liangliang | - |
dc.contributor.author | Cao, Xiaoyan | - |
dc.contributor.author | Chen, Xuebo | - |
dc.contributor.author | Fang, Weihai | - |
dc.contributor.author | Dolg, Michael | - |
dc.date.accessioned | 2020-10-12T08:06:35Z | - |
dc.date.available | 2020-10-12T08:06:35Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 27, p. 7986-7990 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/289066 | - |
dc.description.abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum-chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet–quintet intersystem crossing on the basis of spin–orbit coupling among the sublevels of the involved states. | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie - International Edition | - |
dc.subject | energy transfer | - |
dc.subject | antenna probes | - |
dc.subject | luminescence | - |
dc.subject | ab initio calculations | - |
dc.subject | resonant crossing | - |
dc.title | Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.201701575 | - |
dc.identifier.pmid | 28374566 | - |
dc.identifier.scopus | eid_2-s2.0-85017346394 | - |
dc.identifier.volume | 56 | - |
dc.identifier.issue | 27 | - |
dc.identifier.spage | 7986 | - |
dc.identifier.epage | 7990 | - |
dc.identifier.eissn | 1521-3773 | - |
dc.identifier.isi | WOS:000403839000056 | - |
dc.identifier.issnl | 1433-7851 | - |