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- Publisher Website: 10.1016/j.tetasy.2010.01.015
- Scopus: eid_2-s2.0-77949541229
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Article: Rational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation
Title | Rational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation |
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Authors | |
Issue Date | 2010 |
Citation | Tetrahedron Asymmetry, 2010, v. 21, n. 2, p. 241-246 How to Cite? |
Abstract | The scaffold rigidity of bis(oxazoline) ligands was rationally tuned on the basis of literature information. Diphenylsulfide-linked bis(oxazoline) ligands with a flexible scaffold were efficiently synthesized to test our hypothesis. The improved enantioselectivity in palladium-catalyzed asymmetric allylic alkylation reaction was achieved as we expected. © 2010 Elsevier Ltd. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/291952 |
ISSN | 2016 Impact Factor: 2.126 2020 SCImago Journal Rankings: 0.396 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Du, Xian | - |
dc.contributor.author | Liu, Han | - |
dc.contributor.author | Du, Da Ming | - |
dc.date.accessioned | 2020-11-17T14:55:27Z | - |
dc.date.available | 2020-11-17T14:55:27Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Tetrahedron Asymmetry, 2010, v. 21, n. 2, p. 241-246 | - |
dc.identifier.issn | 0957-4166 | - |
dc.identifier.uri | http://hdl.handle.net/10722/291952 | - |
dc.description.abstract | The scaffold rigidity of bis(oxazoline) ligands was rationally tuned on the basis of literature information. Diphenylsulfide-linked bis(oxazoline) ligands with a flexible scaffold were efficiently synthesized to test our hypothesis. The improved enantioselectivity in palladium-catalyzed asymmetric allylic alkylation reaction was achieved as we expected. © 2010 Elsevier Ltd. All rights reserved. | - |
dc.language | eng | - |
dc.relation.ispartof | Tetrahedron Asymmetry | - |
dc.title | Rational tuning of the rigidity of a ligand scaffold: synthesis of diphenylsulfide-linked bis(oxazoline) ligands and their application in asymmetric allylic alkylation | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.tetasy.2010.01.015 | - |
dc.identifier.scopus | eid_2-s2.0-77949541229 | - |
dc.identifier.volume | 21 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 241 | - |
dc.identifier.epage | 246 | - |
dc.identifier.eissn | 1362-511X | - |
dc.identifier.isi | WOS:000276083200019 | - |
dc.identifier.issnl | 0957-4166 | - |