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Article: Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes
Title | Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes |
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Authors | |
Keywords | Diphenylamine Friedel-crafts alkylation Bis(oxazoline) Dihydroacridine Flexible scaffold Rigid scaffold |
Issue Date | 2010 |
Citation | Letters in Organic Chemistry, 2010, v. 7, n. 2, p. 114-120 How to Cite? |
Abstract | Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric Friedel-Crafts alkylation was obtained through XRD analysis of flexible ligand/ZnCl2 complex, as well as synthesis of dihydroacridine-linked bis(oxazoline) ligands with planar rigid scaffold. A transition state model without NH φ interaction was proposed for the rigid ligands to interpret the inversion of absolute configuration. © 2010 Bentham Science Publishers Ltd. |
Persistent Identifier | http://hdl.handle.net/10722/291962 |
ISSN | 2023 Impact Factor: 0.7 2023 SCImago Journal Rankings: 0.174 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Liu, Han | - |
dc.contributor.author | Wang, Neng Dong | - |
dc.contributor.author | Du, Da Ming | - |
dc.date.accessioned | 2020-11-17T14:55:28Z | - |
dc.date.available | 2020-11-17T14:55:28Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Letters in Organic Chemistry, 2010, v. 7, n. 2, p. 114-120 | - |
dc.identifier.issn | 1570-1786 | - |
dc.identifier.uri | http://hdl.handle.net/10722/291962 | - |
dc.description.abstract | Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric Friedel-Crafts alkylation was obtained through XRD analysis of flexible ligand/ZnCl2 complex, as well as synthesis of dihydroacridine-linked bis(oxazoline) ligands with planar rigid scaffold. A transition state model without NH φ interaction was proposed for the rigid ligands to interpret the inversion of absolute configuration. © 2010 Bentham Science Publishers Ltd. | - |
dc.language | eng | - |
dc.relation.ispartof | Letters in Organic Chemistry | - |
dc.subject | Diphenylamine | - |
dc.subject | Friedel-crafts alkylation | - |
dc.subject | Bis(oxazoline) | - |
dc.subject | Dihydroacridine | - |
dc.subject | Flexible scaffold | - |
dc.subject | Rigid scaffold | - |
dc.title | Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric friedel-crafts alkylation of indole with nitroalkenes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.2174/157017810790796354 | - |
dc.identifier.scopus | eid_2-s2.0-77951482907 | - |
dc.identifier.volume | 7 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 114 | - |
dc.identifier.epage | 120 | - |
dc.identifier.isi | WOS:000275168000006 | - |
dc.identifier.issnl | 1570-1786 | - |