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- Publisher Website: 10.1002/ejoc.201000818
- Scopus: eid_2-s2.0-77956455363
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Article: Synthesis of binaphthyl sulfonimides and their application in the enantioselective Michael addition of ketones to nitroalkenes
| Title | Synthesis of binaphthyl sulfonimides and their application in the enantioselective Michael addition of ketones to nitroalkenes |
|---|---|
| Authors | |
| Keywords | Enantioselectivity Organocatalysis Sulfonamides Alkenes Michael addition |
| Issue Date | 2010 |
| Citation | European Journal of Organic Chemistry, 2010, v. 2010 n. 27, p. 5160-5164 How to Cite? |
| Abstract | Novel types of L-proline-based binaphthyl sulfonimides and sulfonamides were found to be efficient organocatalysts for the asymmetric Michael addition of ketones to nitroalkenes to provide optically active γ-nitroketone derivatives of synthetic and biological importance. After the fine optimization of solvents, temperature, and additive, good to excellent enantioselectivities and diastereoselectivities (71-96%ee, up to >99:1 dr) can be achieved. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Persistent Identifier | http://hdl.handle.net/10722/291988 |
| ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.584 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ban, Shurong | - |
| dc.contributor.author | Du, Da Ming | - |
| dc.contributor.author | Liu, Han | - |
| dc.contributor.author | Yang, Wen | - |
| dc.date.accessioned | 2020-11-17T14:55:32Z | - |
| dc.date.available | 2020-11-17T14:55:32Z | - |
| dc.date.issued | 2010 | - |
| dc.identifier.citation | European Journal of Organic Chemistry, 2010, v. 2010 n. 27, p. 5160-5164 | - |
| dc.identifier.issn | 1434-193X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/291988 | - |
| dc.description.abstract | Novel types of L-proline-based binaphthyl sulfonimides and sulfonamides were found to be efficient organocatalysts for the asymmetric Michael addition of ketones to nitroalkenes to provide optically active γ-nitroketone derivatives of synthetic and biological importance. After the fine optimization of solvents, temperature, and additive, good to excellent enantioselectivities and diastereoselectivities (71-96%ee, up to >99:1 dr) can be achieved. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
| dc.language | eng | - |
| dc.relation.ispartof | European Journal of Organic Chemistry | - |
| dc.subject | Enantioselectivity | - |
| dc.subject | Organocatalysis | - |
| dc.subject | Sulfonamides | - |
| dc.subject | Alkenes | - |
| dc.subject | Michael addition | - |
| dc.title | Synthesis of binaphthyl sulfonimides and their application in the enantioselective Michael addition of ketones to nitroalkenes | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/ejoc.201000818 | - |
| dc.identifier.scopus | eid_2-s2.0-77956455363 | - |
| dc.identifier.volume | 2010 | - |
| dc.identifier.issue | 27 | - |
| dc.identifier.spage | 5160 | - |
| dc.identifier.epage | 5164 | - |
| dc.identifier.eissn | 1099-0690 | - |
| dc.identifier.isi | WOS:000283102700003 | - |
| dc.identifier.issnl | 1099-0690 | - |