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Article: Diameter-selective encapsulation of metallocenes in single-walled carbon nanotubes

TitleDiameter-selective encapsulation of metallocenes in single-walled carbon nanotubes
Authors
Issue Date2005
Citation
Nature Materials, 2005, v. 4, n. 6, p. 481-485 How to Cite?
AbstractThe diameter selective encapsulation of two metallocene compounds bis(cyclopentadienyl) cobalt and bis(ethylcyclopentadienyl) was analyzed in single-walled carbon nanotubes. Electron transfer from the cobalt ions to the nanotubes was directly observed through a change in the charge state of the encapsulated molecule. Two very strong absorption bands for CoCp at 5.277 eV and 4.788 eV were assigned to the metal-to-ligand and ligand-to-metal charge transfer transitions. It was observed that the absorption of CoCp in a relatively wide nanotube was only slightly exothermic. 2 2
Persistent Identifierhttp://hdl.handle.net/10722/298388
ISSN
2023 Impact Factor: 37.2
2023 SCImago Journal Rankings: 14.231
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLi, Lain Jong-
dc.contributor.authorKhlobystov, A. N.-
dc.contributor.authorWiltshire, J. G.-
dc.contributor.authorBriggs, G. A.D.-
dc.contributor.authorNicholas, R. J.-
dc.date.accessioned2021-04-08T03:08:19Z-
dc.date.available2021-04-08T03:08:19Z-
dc.date.issued2005-
dc.identifier.citationNature Materials, 2005, v. 4, n. 6, p. 481-485-
dc.identifier.issn1476-1122-
dc.identifier.urihttp://hdl.handle.net/10722/298388-
dc.description.abstractThe diameter selective encapsulation of two metallocene compounds bis(cyclopentadienyl) cobalt and bis(ethylcyclopentadienyl) was analyzed in single-walled carbon nanotubes. Electron transfer from the cobalt ions to the nanotubes was directly observed through a change in the charge state of the encapsulated molecule. Two very strong absorption bands for CoCp at 5.277 eV and 4.788 eV were assigned to the metal-to-ligand and ligand-to-metal charge transfer transitions. It was observed that the absorption of CoCp in a relatively wide nanotube was only slightly exothermic. 2 2-
dc.languageeng-
dc.relation.ispartofNature Materials-
dc.titleDiameter-selective encapsulation of metallocenes in single-walled carbon nanotubes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1038/nmat1396-
dc.identifier.pmid15908958-
dc.identifier.scopuseid_2-s2.0-20144380980-
dc.identifier.volume4-
dc.identifier.issue6-
dc.identifier.spage481-
dc.identifier.epage485-
dc.identifier.isiWOS:000229502700016-
dc.identifier.issnl1476-1122-

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