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Article: High methane storage capacity in aluminum metal-organic frameworks

TitleHigh methane storage capacity in aluminum metal-organic frameworks
Authors
Issue Date2014
Citation
Journal of the American Chemical Society, 2014, v. 136, n. 14, p. 5271-5274 How to Cite?
AbstractThe use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal-organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm3 cm-3 at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm 3 cm-3 under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm3 cm -3, and between 5 and 80 bar, 230 cm3 cm-3. © 2014 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/303747
ISSN
2020 Impact Factor: 15.419
2020 SCImago Journal Rankings: 7.115
PubMed Central ID

 

DC FieldValueLanguage
dc.contributor.authorGándara, Felipe-
dc.contributor.authorFurukawa, Hiroyasu-
dc.contributor.authorLee, Seungkyu-
dc.contributor.authorYaghi, Omar M.-
dc.date.accessioned2021-09-15T08:25:56Z-
dc.date.available2021-09-15T08:25:56Z-
dc.date.issued2014-
dc.identifier.citationJournal of the American Chemical Society, 2014, v. 136, n. 14, p. 5271-5274-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/303747-
dc.description.abstractThe use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal-organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm3 cm-3 at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm 3 cm-3 under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm3 cm -3, and between 5 and 80 bar, 230 cm3 cm-3. © 2014 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.rightsThis is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.-
dc.titleHigh methane storage capacity in aluminum metal-organic frameworks-
dc.typeArticle-
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1021/ja501606h-
dc.identifier.pmid24661065-
dc.identifier.pmcidPMC4210148-
dc.identifier.scopuseid_2-s2.0-84898001059-
dc.identifier.volume136-
dc.identifier.issue14-
dc.identifier.spage5271-
dc.identifier.epage5274-
dc.identifier.eissn1520-5126-

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