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Article: cis-β-Ru(II)heteroatom-stabilized-carbene complexes supported by tetradentate Schiff-base salen ligand

Titlecis-β-Ru(II)heteroatom-stabilized-carbene complexes supported by tetradentate Schiff-base salen ligand
Authors
Chen, DGuan, XWan, QLow, KHHuang, JS
KeywordsMetal-carbene
Ru(II)-salen
Cis-β complexes
Issue Date2021
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 2021, v. 199, article no. 115073 How to Cite?
DOI: http://dx.doi.org/10.1016/j.poly.2021.115073
AbstractA panel of stable ruthenium carbene complexes bearing a tetradentate salen ligand, with their carbene-C atom adjacent to heteroatom, were synthesized from cis-β-Ru(II)-bis(CO) complex by reacting with the corresponding carbene precursors. These carbene complexes, which were fully characterized by elemental analysis, NMR, IR spectroscopy and X-ray-crystal structure determination, all adopt a cis-β configuration; the heteroatom (N or O) adjacent to the carbene C atom contributes to the high stability of these complexes both in solution and in solid state. DFT calculations were also performed to gain insight into the Ru-Ccarbene bonds.
Persistent Identifierhttp://hdl.handle.net/10722/305286
ISSN
0277-5387
2022 Impact Factor: 2.6
2020 SCImago Journal Rankings: 0.496
ISI Accession Number ID
WOS:000634741700003

 

DC FieldValueLanguage
dc.contributor.authorChen, D-
dc.contributor.authorGuan, X-
dc.contributor.authorWan, Q-
dc.contributor.authorLow, KH-
dc.contributor.authorHuang, JS-
dc.date.accessioned2021-10-20T10:07:16Z-
dc.date.available2021-10-20T10:07:16Z-
dc.date.issued2021-
dc.identifier.citationPolyhedron, 2021, v. 199, article no. 115073-
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/10722/305286-
dc.description.abstractA panel of stable ruthenium carbene complexes bearing a tetradentate salen ligand, with their carbene-C atom adjacent to heteroatom, were synthesized from cis-β-Ru(II)-bis(CO) complex by reacting with the corresponding carbene precursors. These carbene complexes, which were fully characterized by elemental analysis, NMR, IR spectroscopy and X-ray-crystal structure determination, all adopt a cis-β configuration; the heteroatom (N or O) adjacent to the carbene C atom contributes to the high stability of these complexes both in solution and in solid state. DFT calculations were also performed to gain insight into the Ru-Ccarbene bonds.-
dc.languageeng-
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly-
dc.relation.ispartofPolyhedron-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.subjectMetal-carbene-
dc.subjectRu(II)-salen-
dc.subjectCis-β complexes-
dc.titlecis-β-Ru(II)heteroatom-stabilized-carbene complexes supported by tetradentate Schiff-base salen ligand-
dc.typeArticle-
dc.identifier.emailGuan, X: xgguan@hku.hk-
dc.identifier.emailWan, Q: wendyqyw@hku.hk-
dc.identifier.emailLow, KH: khlow@hku.hk-
dc.identifier.emailHuang, JS: jshuang@hku.hk-
dc.identifier.authorityHuang, JS=rp00709-
dc.description.naturepostprint-
dc.identifier.doi10.1016/j.poly.2021.115073-
dc.identifier.scopuseid_2-s2.0-85101095169-
dc.identifier.hkuros327793-
dc.identifier.volume199-
dc.identifier.spagearticle no. 115073-
dc.identifier.epagearticle no. 115073-
dc.identifier.isiWOS:000634741700003-
dc.publisher.placeNetherlands-

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