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Article: Lithium‐Ion Desolvation Induced by Nitrate Additives Reveals New Insights into High Performance Lithium Batteries

TitleLithium‐Ion Desolvation Induced by Nitrate Additives Reveals New Insights into High Performance Lithium Batteries
Authors
Keywordselectrolyte additives
graphite anodes
lithium batteries
lithium solvation
Li–S batteries
Issue Date2021
PublisherWiley-VCH Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/afm
Citation
Advanced Functional Materials, 2021, v. 31 n. 23, p. article no. 2101593 How to Cite?
AbstractElectrolyte additives have been widely used to address critical issues in current metal (ion) battery technologies. While their functions as solid electrolyte interface forming agents are reasonably well-understood, their interactions in the liquid electrolyte environment remain rather elusive. This lack of knowledge represents a significant bottleneck that hinders the development of improved electrolyte systems. Here, the key role of additives in promoting cation (e.g., Li+) desolvation is unraveled. In particular, nitrate anions (NO3−) are found to incorporate into the solvation shells, change the local environment of cations (e.g., Li+) as well as their coordination in the electrolytes. The combination of these effects leads to effective Li+ desolvation and enhanced battery performance. Remarkably, the inexpensive NaNO3 can successfully substitute the widely used LiNO3 offering superior long-term stability of Li+ (de-)intercalation at the graphite anode and suppressed polysulfide shuttle effect at the sulfur cathode, while enhancing the performance of lithium–sulfur full batteries (initial capacity of 1153 mAh g−1 at 0.25C) with Coulombic efficiency of ≈100% over 300 cycles. This work provides important new insights into the unexplored effects of additives and paves the way to developing improved electrolytes for electrochemical energy storage applications.
Persistent Identifierhttp://hdl.handle.net/10722/305371
ISSN
2023 Impact Factor: 18.5
2023 SCImago Journal Rankings: 5.496
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWahyadi, W-
dc.contributor.authorLadelta, V-
dc.contributor.authorTsetseris, L-
dc.contributor.authorAlsabban, MM-
dc.contributor.authorGuo, X-
dc.contributor.authorYengel, E-
dc.contributor.authorFaber, H-
dc.contributor.authorAdibekova, B-
dc.contributor.authorSeitkhan, A-
dc.contributor.authorEmwas, AH-
dc.contributor.authorHedhili, MN-
dc.contributor.authorLi, LJ-
dc.contributor.authorTung, V-
dc.contributor.authorHadjichristidis, N-
dc.contributor.authorAnthopoulos, TD-
dc.contributor.authorMing, J-
dc.date.accessioned2021-10-20T10:08:28Z-
dc.date.available2021-10-20T10:08:28Z-
dc.date.issued2021-
dc.identifier.citationAdvanced Functional Materials, 2021, v. 31 n. 23, p. article no. 2101593-
dc.identifier.issn1616-301X-
dc.identifier.urihttp://hdl.handle.net/10722/305371-
dc.description.abstractElectrolyte additives have been widely used to address critical issues in current metal (ion) battery technologies. While their functions as solid electrolyte interface forming agents are reasonably well-understood, their interactions in the liquid electrolyte environment remain rather elusive. This lack of knowledge represents a significant bottleneck that hinders the development of improved electrolyte systems. Here, the key role of additives in promoting cation (e.g., Li+) desolvation is unraveled. In particular, nitrate anions (NO3−) are found to incorporate into the solvation shells, change the local environment of cations (e.g., Li+) as well as their coordination in the electrolytes. The combination of these effects leads to effective Li+ desolvation and enhanced battery performance. Remarkably, the inexpensive NaNO3 can successfully substitute the widely used LiNO3 offering superior long-term stability of Li+ (de-)intercalation at the graphite anode and suppressed polysulfide shuttle effect at the sulfur cathode, while enhancing the performance of lithium–sulfur full batteries (initial capacity of 1153 mAh g−1 at 0.25C) with Coulombic efficiency of ≈100% over 300 cycles. This work provides important new insights into the unexplored effects of additives and paves the way to developing improved electrolytes for electrochemical energy storage applications.-
dc.languageeng-
dc.publisherWiley-VCH Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/afm-
dc.relation.ispartofAdvanced Functional Materials-
dc.rightsAccepted (peer-reviewed) Version This is the peer reviewed version of the following article: [Advanced Functional Materials, 2021, v. 31 n. 23, p. article no. 2101593], which has been published in final form at [http://dx.doi.org/10.1002/adfm.202101593]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjectelectrolyte additives-
dc.subjectgraphite anodes-
dc.subjectlithium batteries-
dc.subjectlithium solvation-
dc.subjectLi–S batteries-
dc.titleLithium‐Ion Desolvation Induced by Nitrate Additives Reveals New Insights into High Performance Lithium Batteries-
dc.typeArticle-
dc.identifier.emailLi, LJ: lanceli1@hku.hk-
dc.identifier.authorityLi, LJ=rp02799-
dc.description.naturepostprint-
dc.identifier.doi10.1002/adfm.202101593-
dc.identifier.scopuseid_2-s2.0-85103975892-
dc.identifier.hkuros327590-
dc.identifier.volume31-
dc.identifier.issue23-
dc.identifier.spagearticle no. 2101593-
dc.identifier.epagearticle no. 2101593-
dc.identifier.isiWOS:000635971000001-
dc.publisher.placeGermany-

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