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Article: A molecular chameleon: Chromophoric sensing by a self-complexing molecular assembly

TitleA molecular chameleon: Chromophoric sensing by a self-complexing molecular assembly
Authors
KeywordsChromophores
Molecular devices
Nanostructures
Receptors
Supramolecular chemistry
Issue Date1998
Citation
Angewandte Chemie - International Edition, 1998, v. 37, n. 7, p. 975-979 How to Cite?
AbstractA color change from purple to green takes place on addition of tetrathiafulvalene (TTF) to the macrobicyclic receptor 14+, which is composed of a cyclobis(para-quat-p-phenylene) tetracation that shares one of its paraphenylene rings with a 1,5-naphthoparaphenylene-[36]crown-10 macrocycle. The TTF molecule forces the macrobicycle to turn inside out and displaces the self-complexed 1,5-dioxynaphthalene ring system from the center of the tetracationic cyclophane.
Persistent Identifierhttp://hdl.handle.net/10722/332430
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300

 

DC FieldValueLanguage
dc.contributor.authorWolf, Reinhard-
dc.contributor.authorAsakawa, Masumi-
dc.contributor.authorAshton, Peter R.-
dc.contributor.authorGómez-López, Marcos-
dc.contributor.authorHamers, Christoph-
dc.contributor.authorMenzer, Stephan-
dc.contributor.authorParsons, Ian W.-
dc.contributor.authorSpencer, Neil-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorTolley, Malcolm S.-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:11:25Z-
dc.date.available2023-10-06T05:11:25Z-
dc.date.issued1998-
dc.identifier.citationAngewandte Chemie - International Edition, 1998, v. 37, n. 7, p. 975-979-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/332430-
dc.description.abstractA color change from purple to green takes place on addition of tetrathiafulvalene (TTF) to the macrobicyclic receptor 14+, which is composed of a cyclobis(para-quat-p-phenylene) tetracation that shares one of its paraphenylene rings with a 1,5-naphthoparaphenylene-[36]crown-10 macrocycle. The TTF molecule forces the macrobicycle to turn inside out and displaces the self-complexed 1,5-dioxynaphthalene ring system from the center of the tetracationic cyclophane.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectChromophores-
dc.subjectMolecular devices-
dc.subjectNanostructures-
dc.subjectReceptors-
dc.subjectSupramolecular chemistry-
dc.titleA molecular chameleon: Chromophoric sensing by a self-complexing molecular assembly-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/(SICI)1521-3773(19980420)37:7<975::AID-ANIE975>3.0.CO;2-L-
dc.identifier.scopuseid_2-s2.0-0031961088-
dc.identifier.volume37-
dc.identifier.issue7-
dc.identifier.spage975-
dc.identifier.epage979-

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