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Article: A [2]catenane-based solid state electronically reconfigurable switch

TitleA [2]catenane-based solid state electronically reconfigurable switch
Authors
Issue Date2000
Citation
Science, 2000, v. 289, n. 5482, p. 1172-1175 How to Cite?
AbstractA solid state, electronically addressable, bistable [2]catenane-based molecular switching device was fabricated from a single monolayer of the [2]catenane, anchored with phospholipid counterions, and sandwiched between an n-type polycrystalline silicon bottom electrode and a metallic top electrode. The device exhibits hysteretic (bistable) current/voltage characteristics. The switch is opened at +2 volts, closed at -2 volts, and read at -0.1 volt and may be recycled many times under ambient conditions. A mechanochemical mechanism for the action of the switch is presented and shown to be consistent with temperature-dependent measurements of the device operation.
Persistent Identifierhttp://hdl.handle.net/10722/332480
ISSN
2023 Impact Factor: 44.7
2023 SCImago Journal Rankings: 11.902
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCollier, C. P.-
dc.contributor.authorMattersteig, G.-
dc.contributor.authorWong, E. W.-
dc.contributor.authorLuo, Y.-
dc.contributor.authorBeverly, K.-
dc.contributor.authorSampaio, J.-
dc.contributor.authorRaymo, F. M.-
dc.contributor.authorStoddart, J. F.-
dc.contributor.authorHeath, J. R.-
dc.date.accessioned2023-10-06T05:11:50Z-
dc.date.available2023-10-06T05:11:50Z-
dc.date.issued2000-
dc.identifier.citationScience, 2000, v. 289, n. 5482, p. 1172-1175-
dc.identifier.issn0036-8075-
dc.identifier.urihttp://hdl.handle.net/10722/332480-
dc.description.abstractA solid state, electronically addressable, bistable [2]catenane-based molecular switching device was fabricated from a single monolayer of the [2]catenane, anchored with phospholipid counterions, and sandwiched between an n-type polycrystalline silicon bottom electrode and a metallic top electrode. The device exhibits hysteretic (bistable) current/voltage characteristics. The switch is opened at +2 volts, closed at -2 volts, and read at -0.1 volt and may be recycled many times under ambient conditions. A mechanochemical mechanism for the action of the switch is presented and shown to be consistent with temperature-dependent measurements of the device operation.-
dc.languageeng-
dc.relation.ispartofScience-
dc.titleA [2]catenane-based solid state electronically reconfigurable switch-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1126/science.289.5482.1172-
dc.identifier.scopuseid_2-s2.0-0034682887-
dc.identifier.volume289-
dc.identifier.issue5482-
dc.identifier.spage1172-
dc.identifier.epage1175-
dc.identifier.isiWOS:000088866600036-

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