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Article: Translational isomerism in a [3]catenane and a [3]rotaxane

TitleTranslational isomerism in a [3]catenane and a [3]rotaxane
Authors
Chiu, Sheng HsienElizarov, Arkadij M.Glink, Peter T.Stoddart, J. Fraser
Issue Date2002
Citation
Organic Letters, 2002, v. 4, n. 21, p. 3561-3564 How to Cite?
DOI: http://dx.doi.org/10.1021/ol026464e
Abstract(graph presented) Post-assembly covalent modification using Wittig chemistry of [2]rotaxane ylides, wherein NH2+ centers in the dumbbell-shaped components are recognized by dibenzo[24]crown-8 (DB24C8) rings, has afforded a [3]catenane and a [3]rotaxane with a precise and synthetically prescribed shortage of DB24C8 rings. The nondegenerate pairs of translational isomers present in both of these interlocked molecular compounds provide the fundamental platform on which to construct sensory devices and nanochemomechanical systems.
Persistent Identifierhttp://hdl.handle.net/10722/332519
ISSN
1523-7060
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID
WOS:000178522700003

 

DC FieldValueLanguage
dc.contributor.authorChiu, Sheng Hsien-
dc.contributor.authorElizarov, Arkadij M.-
dc.contributor.authorGlink, Peter T.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:12:09Z-
dc.date.available2023-10-06T05:12:09Z-
dc.date.issued2002-
dc.identifier.citationOrganic Letters, 2002, v. 4, n. 21, p. 3561-3564-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332519-
dc.description.abstract(graph presented) Post-assembly covalent modification using Wittig chemistry of [2]rotaxane ylides, wherein NH2+ centers in the dumbbell-shaped components are recognized by dibenzo[24]crown-8 (DB24C8) rings, has afforded a [3]catenane and a [3]rotaxane with a precise and synthetically prescribed shortage of DB24C8 rings. The nondegenerate pairs of translational isomers present in both of these interlocked molecular compounds provide the fundamental platform on which to construct sensory devices and nanochemomechanical systems.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleTranslational isomerism in a [3]catenane and a [3]rotaxane-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol026464e-
dc.identifier.pmid12375887-
dc.identifier.scopuseid_2-s2.0-0037126234-
dc.identifier.volume4-
dc.identifier.issue21-
dc.identifier.spage3561-
dc.identifier.epage3564-
dc.identifier.isiWOS:000178522700003-

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