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- Publisher Website: 10.1002/smll.200400070
- Scopus: eid_2-s2.0-22144442558
- PMID: 17193471
- WOS: WOS:000229118000014
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Article: Single-walled carbon nanotubes under the influence of dynamic coordination and supramolecular chemistry
Title | Single-walled carbon nanotubes under the influence of dynamic coordination and supramolecular chemistry |
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Authors | |
Keywords | Carbon nanotubes Coordination chemistry Devices Self-assembly Separation science |
Issue Date | 2005 |
Citation | Small, 2005, v. 1, n. 4, p. 452-461 How to Cite? |
Abstract | A dynamic coordinative-directed solubilization of single-walled carbon nanotubes (SWNTs) in aqueous solutions has been achieved through a combination of a Znll metalloporphyrin complex and a cis-protected Pd ll complex, which are believed to form charged acyclic and/or cyclic adducts on or around the side walls of SWNTs. The solubilization of SWNTs in aqueous solution only occurs when these acyclic and/or cyclic complexes are allowed to enter simultaneously into a self-assembly process with SWNTs under mild conditions. The aqueous solubility properties that these dynamic complexes confer upon SWNTs are believed to involve noncovalent bonding interactions between the two entities. They have been probed in solution using ultraviolet and visible absorption spectroscopy and in thin films using high-resolution transmission electron microscopy. The supramolecular electronic effects that the individual components of their acyclic and/or cyclic complexes impart upon a single semiconducting SWNT have been probed within a nanotuhe field-effect transistor device. © 2005 Wiley VCH Verlag GmbH & Co. KGaA. |
Persistent Identifier | http://hdl.handle.net/10722/332611 |
ISSN | 2023 Impact Factor: 13.0 2023 SCImago Journal Rankings: 3.348 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chichak, Kelly S. | - |
dc.contributor.author | Star, Alexander | - |
dc.contributor.author | Virginia, M. | - |
dc.contributor.author | Altoé, P. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:12:52Z | - |
dc.date.available | 2023-10-06T05:12:52Z | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Small, 2005, v. 1, n. 4, p. 452-461 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332611 | - |
dc.description.abstract | A dynamic coordinative-directed solubilization of single-walled carbon nanotubes (SWNTs) in aqueous solutions has been achieved through a combination of a Znll metalloporphyrin complex and a cis-protected Pd ll complex, which are believed to form charged acyclic and/or cyclic adducts on or around the side walls of SWNTs. The solubilization of SWNTs in aqueous solution only occurs when these acyclic and/or cyclic complexes are allowed to enter simultaneously into a self-assembly process with SWNTs under mild conditions. The aqueous solubility properties that these dynamic complexes confer upon SWNTs are believed to involve noncovalent bonding interactions between the two entities. They have been probed in solution using ultraviolet and visible absorption spectroscopy and in thin films using high-resolution transmission electron microscopy. The supramolecular electronic effects that the individual components of their acyclic and/or cyclic complexes impart upon a single semiconducting SWNT have been probed within a nanotuhe field-effect transistor device. © 2005 Wiley VCH Verlag GmbH & Co. KGaA. | - |
dc.language | eng | - |
dc.relation.ispartof | Small | - |
dc.subject | Carbon nanotubes | - |
dc.subject | Coordination chemistry | - |
dc.subject | Devices | - |
dc.subject | Self-assembly | - |
dc.subject | Separation science | - |
dc.title | Single-walled carbon nanotubes under the influence of dynamic coordination and supramolecular chemistry | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/smll.200400070 | - |
dc.identifier.pmid | 17193471 | - |
dc.identifier.scopus | eid_2-s2.0-22144442558 | - |
dc.identifier.volume | 1 | - |
dc.identifier.issue | 4 | - |
dc.identifier.spage | 452 | - |
dc.identifier.epage | 461 | - |
dc.identifier.eissn | 1613-6829 | - |
dc.identifier.isi | WOS:000229118000014 | - |