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- Publisher Website: 10.1002/chem.200501028
- Scopus: eid_2-s2.0-33646501955
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Article: Self-assembly with block copolymers through metal coordination of SCS-PdII pincer complexes and pseudorotaxane formation
| Title | Self-assembly with block copolymers through metal coordination of SCS-Pd<sup>II</sup> pincer complexes and pseudorotaxane formation |
|---|---|
| Authors | |
| Keywords | Copolymerization Crown compounds Palladium Pincer complexes Supramolecular chemistry |
| Issue Date | 2006 |
| Citation | Chemistry - A European Journal, 2006, v. 12, n. 14, p. 3789-3797 How to Cite? |
| Abstract | Poly(norbornene)-based block copolymers containing side chains of palladated pincer complexes/dibenzo[24]crown-8 or palladated pincer complexes/dibenzylammonium salts were synthesized. Noncovalent functionalization was accomplished with their corresponding recognition units through simple 1:1 addition with association constants (Ka) greater than 10 5M-1. The self-assembly processes were monitored by using both 1H NMR spectroscopy and isothermal titration calorimetry. In all cases, we found that the self-assembly of the recognition units along each polymer block does not preclude the self-assembly processes along the other block. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Persistent Identifier | http://hdl.handle.net/10722/332669 |
| ISSN | 2023 Impact Factor: 3.9 2023 SCImago Journal Rankings: 1.058 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | South, Clinton R. | - |
| dc.contributor.author | Higley, Mary Nell | - |
| dc.contributor.author | Leung, Ken C.F. | - |
| dc.contributor.author | Lanari, Daniela | - |
| dc.contributor.author | Nelson, Alshakim | - |
| dc.contributor.author | Grubbs, Robert H. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Weck, Marcus | - |
| dc.date.accessioned | 2023-10-06T05:13:22Z | - |
| dc.date.available | 2023-10-06T05:13:22Z | - |
| dc.date.issued | 2006 | - |
| dc.identifier.citation | Chemistry - A European Journal, 2006, v. 12, n. 14, p. 3789-3797 | - |
| dc.identifier.issn | 0947-6539 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332669 | - |
| dc.description.abstract | Poly(norbornene)-based block copolymers containing side chains of palladated pincer complexes/dibenzo[24]crown-8 or palladated pincer complexes/dibenzylammonium salts were synthesized. Noncovalent functionalization was accomplished with their corresponding recognition units through simple 1:1 addition with association constants (Ka) greater than 10 5M-1. The self-assembly processes were monitored by using both 1H NMR spectroscopy and isothermal titration calorimetry. In all cases, we found that the self-assembly of the recognition units along each polymer block does not preclude the self-assembly processes along the other block. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Chemistry - A European Journal | - |
| dc.subject | Copolymerization | - |
| dc.subject | Crown compounds | - |
| dc.subject | Palladium | - |
| dc.subject | Pincer complexes | - |
| dc.subject | Supramolecular chemistry | - |
| dc.title | Self-assembly with block copolymers through metal coordination of SCS-Pd<sup>II</sup> pincer complexes and pseudorotaxane formation | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/chem.200501028 | - |
| dc.identifier.scopus | eid_2-s2.0-33646501955 | - |
| dc.identifier.volume | 12 | - |
| dc.identifier.issue | 14 | - |
| dc.identifier.spage | 3789 | - |
| dc.identifier.epage | 3797 | - |
| dc.identifier.eissn | 1521-3765 | - |
| dc.identifier.isi | WOS:000237621900012 | - |