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Article: Template-directed one-step synthesis of cyclic trimers by ADMET

TitleTemplate-directed one-step synthesis of cyclic trimers by ADMET
Authors
Hou, HongyiLeung, Ken C.F.Lanari, DanielaNelson, AlshakimStoddart, J. FraserGrubbs, Robert H.
Issue Date2006
Citation
Journal of the American Chemical Society, 2006, v. 128, n. 48, p. 15358-15359 How to Cite?
DOI: http://dx.doi.org/10.1021/ja065572j
AbstractA trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium-alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry. Copyright © 2006 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332713
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:000242367000003

 

DC FieldValueLanguage
dc.contributor.authorHou, Hongyi-
dc.contributor.authorLeung, Ken C.F.-
dc.contributor.authorLanari, Daniela-
dc.contributor.authorNelson, Alshakim-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorGrubbs, Robert H.-
dc.date.accessioned2023-10-06T05:13:41Z-
dc.date.available2023-10-06T05:13:41Z-
dc.date.issued2006-
dc.identifier.citationJournal of the American Chemical Society, 2006, v. 128, n. 48, p. 15358-15359-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/332713-
dc.description.abstractA trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium-alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry. Copyright © 2006 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleTemplate-directed one-step synthesis of cyclic trimers by ADMET-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja065572j-
dc.identifier.pmid17131986-
dc.identifier.scopuseid_2-s2.0-33845327559-
dc.identifier.volume128-
dc.identifier.issue48-
dc.identifier.spage15358-
dc.identifier.epage15359-
dc.identifier.isiWOS:000242367000003-

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