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Article: A clicked bistable [2]rotaxane

TitleA clicked bistable [2]rotaxane
Authors
Issue Date2007
Citation
Organic Letters, 2007, v. 9, n. 7, p. 1287-1290 How to Cite?
AbstractA universal diazide-terminated polyether, incorporating tetrathiafulvalene (TTF, green) and 1,5-dioxynaphthalene (DNP, red) units, was prepared and subsequently employed in the template-directed synthesis of a switchable donor/acceptor [2]rotaxane. The triazole rings (magenta), which are introduced into the rotaxane during requisite click reactions, do not present themselves as competing recognition sites for the tetracationic cyclophane (blue) as it is induced to switch between the TTF unit, when it becomes dicationic (green adorned with yellow extremities), and the DNP unit. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332724
ISSN
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorAprahamian, Ivan-
dc.contributor.authorDichtel, William R.-
dc.contributor.authorIkeda, Taichi-
dc.contributor.authorHeath, James R.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:13:47Z-
dc.date.available2023-10-06T05:13:47Z-
dc.date.issued2007-
dc.identifier.citationOrganic Letters, 2007, v. 9, n. 7, p. 1287-1290-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332724-
dc.description.abstractA universal diazide-terminated polyether, incorporating tetrathiafulvalene (TTF, green) and 1,5-dioxynaphthalene (DNP, red) units, was prepared and subsequently employed in the template-directed synthesis of a switchable donor/acceptor [2]rotaxane. The triazole rings (magenta), which are introduced into the rotaxane during requisite click reactions, do not present themselves as competing recognition sites for the tetracationic cyclophane (blue) as it is induced to switch between the TTF unit, when it becomes dicationic (green adorned with yellow extremities), and the DNP unit. © 2007 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleA clicked bistable [2]rotaxane-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol070052u-
dc.identifier.scopuseid_2-s2.0-34147151108-
dc.identifier.volume9-
dc.identifier.issue7-
dc.identifier.spage1287-
dc.identifier.epage1290-
dc.identifier.isiWOS:000245084300029-

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