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- Publisher Website: 10.1039/C39870001054
- Scopus: eid_2-s2.0-37049080118
- WOS: WOS:A1987J524400005
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Article: A comparison of the receptor stereochemistry in [Pt(bipy)(NH 3 )2 ·dinaphtho-30-crown-10][PF6 ] 2 and [Diquat·dinaphtho-30-crown-10][PF6 ] 2 (bipy = 2,2′-bipyridine)
| Title | A comparison of the receptor stereochemistry in [Pt(bipy)(NH <inf>3</inf>)<inf>2</inf>·dinaphtho-30-crown-10][PF<inf>6</inf>] <inf>2</inf> and [Diquat·dinaphtho-30-crown-10][PF<inf>6</inf>] <inf>2</inf> (bipy = 2,2′-bipyridine) |
|---|---|
| Authors | |
| Issue Date | 1987 |
| Citation | Journal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1054-1058 How to Cite? |
| Abstract | X-Ray crystallography and 1H n.m.r. spectroscopy have revealed dramatic differences in the binding of [Pt(bipy)(NH3) 2]2+ and [Diquat]2+ dications by dinaphtho-30-crown-10 (DN30C10) with the platinum complex adopting a slewed position, apparently in order to maximise overlap between the π-arene systems in the receptor and in the complex, whereas the Diquat dication adopts a symmetrical position more consistent with maximisation of Coulombic interactions. |
| Persistent Identifier | http://hdl.handle.net/10722/332767 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Allwood, Billy L. | - |
| dc.contributor.author | Colquhoun, Howard M. | - |
| dc.contributor.author | Doughty, Simon M. | - |
| dc.contributor.author | Kohnke, Franz H. | - |
| dc.contributor.author | Slawin, Alexandra M.Z. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.contributor.author | Zarzycki, Ryszard | - |
| dc.date.accessioned | 2023-10-06T05:14:07Z | - |
| dc.date.available | 2023-10-06T05:14:07Z | - |
| dc.date.issued | 1987 | - |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1054-1058 | - |
| dc.identifier.issn | 0022-4936 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332767 | - |
| dc.description.abstract | X-Ray crystallography and 1H n.m.r. spectroscopy have revealed dramatic differences in the binding of [Pt(bipy)(NH3) 2]2+ and [Diquat]2+ dications by dinaphtho-30-crown-10 (DN30C10) with the platinum complex adopting a slewed position, apparently in order to maximise overlap between the π-arene systems in the receptor and in the complex, whereas the Diquat dication adopts a symmetrical position more consistent with maximisation of Coulombic interactions. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | - |
| dc.title | A comparison of the receptor stereochemistry in [Pt(bipy)(NH <inf>3</inf>)<inf>2</inf>·dinaphtho-30-crown-10][PF<inf>6</inf>] <inf>2</inf> and [Diquat·dinaphtho-30-crown-10][PF<inf>6</inf>] <inf>2</inf> (bipy = 2,2′-bipyridine) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/C39870001054 | - |
| dc.identifier.scopus | eid_2-s2.0-37049080118 | - |
| dc.identifier.issue | 14 | - |
| dc.identifier.spage | 1054 | - |
| dc.identifier.epage | 1058 | - |
| dc.identifier.isi | WOS:A1987J524400005 | - |